64545-08-0

Upstream product

• 629-27-6 1-Iodooctane 
• 766-77-8 Dimethylphenylsilane 
• 111-66-0 oct-1-ene 
• 124-13-0 Octanal 
• 111-87-5 octanol 
• 71091-89-9 n-octyl triflate 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 111-83-1 1-bromo-octane 
• 111-85-3 n-chlorooctane 
• 124-11-8 non-1-ene 
• 768-33-2 phenyldimethylsilyl chloride 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 201230-82-2 carbon monoxide 
• 261907-79-3 1-(dimethyl(phenyl)silyl)-N,N,N',N'-tetraisopropylboranediamine 

Relevant academic research and scientific papers

A Highly Fluorous Room-Temperature Ionic Liquid Exhibiting Fluorous Biphasic Behavior and Its Use in Catalyst Recycling

(Matrix Presented) A novel fluorous room-temperature ionic liquid, 1-butyl-3-methyl-imidazolium tetrakis[p-{dimethyl(1H,1H,2H,2H-perfluorooctyl)silyl}phenyl]-borate (1), was used as a solvent for the homogeneous hydrosilylation of 1-octene catalyzed by a

Microreactor utilizing a vertically-aligned carbon nanotube array grown inside the channels

We have fabricated a microreactor incorporating vertically-aligned carbon nanotubes supporting Pt nanoparticles and found that the presence of aligned nanotubes significantly enhances the catalytic reaction and extends the catalyst lifetime as compared with conventional microreactors using a Pt metal film or Pt nanoparticles directly deposited on the channel walls. The Royal Society of Chemistry.

The two faces of platinum hydrospirophosphorane complexes—Not only relevant catalysts but cytotoxic compounds as well

Platinum complexes [PtCl2(L)] L = L1, L2 with symmetrical HP (OCH2CMe2NH)2 (L1) and unsymmetrical HP(OCMe2CMe2O)(OCH2CMe2NH) (L2) hydrospirophosphorane (HSP) ligands were demonstrated to play a dual role of catalysts and cytotoxic compounds as well. The structure of new complex [PtCl2(L2)] was confirmed by physicochemical and spectroscopic methods, as well as single X-ray diffraction studies for [PtCl2{P (OCMe2CMe2O)(OCH2CMe2NH2)}]. HSP ligand coordinated to the platinum center in bidentate κ2-P,NH2 chelating mode of fashion. Both complexes were found to exhibit catalytic activity for Heck cross-coupling reactions of iodobenzene with substituted styrenes, with good conversion and yield of stilbenes. Moreover, complexes have been applied as excellent catalysts for highly regioselective hydrosilylation of aromatic and aliphatic terminal olefins, and acetylenes terminal and internal as well. On the other hand, the preliminary biological studies revealed that in the presence of foretinib, drug candidate in clinical trials for the treatment of cancer, platinum complexes revealed increased synergistic effect and efficiently decreased the number of viable cells of triple negative breast cancer MDA-MB-231 cell line.

Accelerated Anti-Markovnikov Alkene Hydrosilylation with Humic-Acid-Supported Electron-Deficient Platinum Single Atoms

The hydrosilylation reaction is one of the largest-scale applications of homogeneous catalysis, and Pt homogeneous catalysts have been widely used in this reaction for the commercial manufacture of silicon products. However, homogeneous Pt catalysts result in considerable problems, such as undesired side reactions, unacceptable catalyst residues and disposable platinum consumption. Here, we synthesized electron-deficient Pt single atoms supported on humic matter (Pt1@AHA_U_400), and the catalyst was used in hydrosilylation reactions, which showed super activity (turnover frequency as high as 3.0×107 h?1) and selectivity (>99 %). Density functional theory calculations reveal that the high performance of the catalyst results from the atomic dispersion of Pt and the electron deficiency of the Pt1 atoms, which is different from conventional Pt nanoscale catalysts. Excellent performance is maintained during recycle experiments, indicating the high stability of the catalyst.

Cobalt bis(2-ethylhexanoate) and terpyridine derivatives as catalysts for the hydrosilylation of olefins

A simple method for the hydrosilylation of olefins by using air-stable cobalt catalysts is developed. The catalyst system is composed of simple, cheap, and readily available cobalt(II) salts and well-defined terpyridine derivatives as cocatalysts or ligands, and the hydrosilylation processes can be processed smoothly under mild conditions without either Grignard reagents or NaHBEt3 as activator.

Highly active cobalt complex catalysts used for alkene hydrosilylation

A series of nitrogen phosphine ligands were synthesized, and the hydrosilylation reaction of alkenes catalyzed using MCl2 in the presence of these ligands was investigated. FeCl2/1(N1, N1, N2, N2-Tetrakis[(diphenylphosphino)methyl]ethane-1,2-diamine) showed low catalytic activity. MnCl2/1, CrCl3/1 and NiCl2/1 showed some catalytic activity. The CoCl2/N,P-ligand catalyst system showed high activity as well as excellent selectivity (The selectivity of the β-adduct was ~100%.) in the hydrosilylation reaction. CoCl2/1 showed the highest catalytic activity (~ >99.9% conversion of 1-octene). Additionally, no α-adduct, dehydrogenative silylation product and octane were detected.

Copper-Photocatalyzed Hydrosilylation of Alkynes and Alkenes under Continuous Flow

Herein, the photocatalytic hydrosilylation of alkynes and alkenes under continuous flow conditions is described. By using 0.2 mol % of the developed [Cu(dmp)(XantphosTEPD)]PF6 under blue LEDs irradiation, a large panel of alkenes and alkynes was hydrosilylated in good to excellent yields with a large functional group tolerance. The mechanism of the reaction was studied, and a plausible scenario was suggested.

Cyclic metal(oid) clusters control platinum-catalysed hydrosilylation reactions: From soluble to zeolite and MOF catalysts

The Pt-catalysed addition of silanes to functional groups such as alkenes, alkynes, carbonyls and alcohols, i.e. the hydrosilylation reaction, is a fundamental transformation in industrial and academic chemistry, often claimed as the most important application of Pt catalysts in solution. However, the exact nature of the Pt active species and its mechanism of action is not well understood yet, particularly regarding regioselectivity. Here, experimental and computational studies together with an ad hoc graphical method show that the hydroaddition of alkynes proceeds through Pt-Si-H clusters of 3-5 atoms (metal(oid) association) in parts per million amounts (ppm), which decrease the energy of the transition state and direct the regioselectivity of the reaction. Based on these findings, new extremely-active (ppm) microporous solid catalysts for the hydrosilylation of alkynes, alkenes and alcohols have been developed, paving the way for more environmentally-benign industrial applications. This journal is

Regioselective hydrosilylation of olefins catalyzed by co-iminobipyridine complexes: The role of cyclohexyl substituent on the imino nitrogen

Regioselective hydrosilylation of aliphatic olefins catalyzed by Co-iminobipyridine complexes, CoRa, were investigated, where R indicates a substituent on the imino nitrogen in an iminobipyridine ligand (iminobypyridine = [2,2¤-bpy]-6-C(Me)=N-R). Synthese

Synthesis of Alkyl Silanes via Reaction of Unactivated Alkyl Chlorides and Triflates with Silyl Lithium Reagents

The reaction of unactivated secondary and primary alkyl chlorides as well as primary alkyl triflates with silyl lithium reagents to access tetraorganosilanes is reported. These nucleophilic substitutions proceed in the absence of any transition metal catalyst under mild conditions in moderate to very good yields. The silyl lithium reagents are readily generated from the corresponding commercially available chlorosilanes. Enantioenriched secondary alkyl chlorides react with high stereospecificity under inversion of configuration.