64545-08-0

Basic information

• Product Name: Silane, dimethyloctylphenyl-
• CAS NO: 64545-08-0
• Molecular Formula: C16H28Si
• Molecular Weight: 248.484
• Mol File: 64545-08-0.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: Silane, dimethyloctylphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, dimethyloctylphenyl-(64545-08-0)
• EPA Substance Registry System: Silane, dimethyloctylphenyl-(64545-08-0)

Safety Data

• Hazardous Substances Data: 64545-08-0(Hazardous Substances Data)

Upstream product

• 111-66-0 oct-1-ene 
• 766-77-8 Dimethylphenylsilane 
• 124-11-8 non-1-ene 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 768-33-2 phenyldimethylsilyl chloride 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 71091-89-9 n-octyl triflate 
• 111-85-3 n-chlorooctane 
• 629-27-6 1-Iodooctane 
• 201230-82-2 carbon monoxide 
• 124-13-0 Octanal 
• 111-87-5 octanol 
• 111-83-1 1-bromo-octane 
• 261907-79-3 1-(dimethyl(phenyl)silyl)-N,N,N',N'-tetraisopropylboranediamine 

Relevant articles and documents

A Highly Fluorous Room-Temperature Ionic Liquid Exhibiting Fluorous Biphasic Behavior and Its Use in Catalyst Recycling

(Matrix Presented) A novel fluorous room-temperature ionic liquid, 1-butyl-3-methyl-imidazolium tetrakis[p-{dimethyl(1H,1H,2H,2H-perfluorooctyl)silyl}phenyl]-borate (1), was used as a solvent for the homogeneous hydrosilylation of 1-octene catalyzed by a

The two faces of platinum hydrospirophosphorane complexes—Not only relevant catalysts but cytotoxic compounds as well

Platinum complexes [PtCl2(L)] L = L1, L2 with symmetrical HP (OCH2CMe2NH)2 (L1) and unsymmetrical HP(OCMe2CMe2O)(OCH2CMe2NH) (L2) hydrospirophosphorane (HSP) ligands were demonstrated to play a dual role of catalysts and cytotoxic compounds as well. The structure of new complex [PtCl2(L2)] was confirmed by physicochemical and spectroscopic methods, as well as single X-ray diffraction studies for [PtCl2{P (OCMe2CMe2O)(OCH2CMe2NH2)}]. HSP ligand coordinated to the platinum center in bidentate κ2-P,NH2 chelating mode of fashion. Both complexes were found to exhibit catalytic activity for Heck cross-coupling reactions of iodobenzene with substituted styrenes, with good conversion and yield of stilbenes. Moreover, complexes have been applied as excellent catalysts for highly regioselective hydrosilylation of aromatic and aliphatic terminal olefins, and acetylenes terminal and internal as well. On the other hand, the preliminary biological studies revealed that in the presence of foretinib, drug candidate in clinical trials for the treatment of cancer, platinum complexes revealed increased synergistic effect and efficiently decreased the number of viable cells of triple negative breast cancer MDA-MB-231 cell line.

Copper-Photocatalyzed Hydrosilylation of Alkynes and Alkenes under Continuous Flow

Herein, the photocatalytic hydrosilylation of alkynes and alkenes under continuous flow conditions is described. By using 0.2 mol % of the developed [Cu(dmp)(XantphosTEPD)]PF6 under blue LEDs irradiation, a large panel of alkenes and alkynes was hydrosilylated in good to excellent yields with a large functional group tolerance. The mechanism of the reaction was studied, and a plausible scenario was suggested.

Cobalt bis(2-ethylhexanoate) and terpyridine derivatives as catalysts for the hydrosilylation of olefins

A simple method for the hydrosilylation of olefins by using air-stable cobalt catalysts is developed. The catalyst system is composed of simple, cheap, and readily available cobalt(II) salts and well-defined terpyridine derivatives as cocatalysts or ligands, and the hydrosilylation processes can be processed smoothly under mild conditions without either Grignard reagents or NaHBEt3 as activator.