64596-17-4Relevant academic research and scientific papers
Diene Oligomerization. XV. Palladiumcomplexcatalyzed Telomerization of Butadiene with Amines and Dimerization in the Presence of Ketoximes
Beger, J.,Meier, F.
, p. 69 - 80 (2007/10/02)
Butadiene reacts with primary or secondary amines and with the homogeneous catalytic system bis-acetylacetonatopalladium-(II)/triphenylphosphine to form 1-amino-octa-2,7-dienes.The rate and the selectivity of the reaction increase in presence of cocatalysts as triarylphosphates instead of triphenylphosphine and if the reaction proceeds in a protic media - in alcohols, water or lower carboxylic acids.A number of 1-aminoocta-2,7-dienes were prepared.If oximes act as organic nitrogen compounds, only n-octa-1,3,7-triene is selectively formed.Schiff' bases aldolisate under the conditions of the reaction.
