646-20-8Relevant academic research and scientific papers
The First Versatile and Practical Building Blocks Equivalent to the Synthon of Monofluoromethylene Dicarbanion
Takeuchi, Yoshio,Nagata, Kazuhiro,Koizumi, Toru
, p. 5061 - 5063 (2007/10/02)
New monofluorinated synthons have been prepared.The use of α-fluoro-α-nitro carboxylic esters as versatile building blocks was demonstrated by their conversion to various monofluorinated compounds via fluoromethyl anion and fluoromethylene dianion equivalents.
Ameliorations et simplifications de la synthese de nitriles par alkylation de l'anion cyanure: catalyse par transfert de phase solide-liquide sans solvant
Bram, G.,Loupy, A.,Pedoussaut, M.
, p. 124 - 128 (2007/10/02)
Alkyl cyanides are obtained in very good yields and under mild conditions by reacting finely ground KCN and the corresponding alkyl halides in the presence of catalytic amounts of tetraalkylammonium salt (Aliquat 336).The addition of small amount of water (1 equivalent) is necessary.
