64666-62-2

Upstream product

• 100-39-0 benzyl bromide 
• 66-71-7 1,10-Phenanthroline 
• 114632-08-5 (1,10-phenanthroline)2Cu(tetrahydroborate) 
• 25753-84-8 (1,10-phenanthroline)(triphenylphosphine)CuBr 
• 80711-23-5 (1,10-phenanthroline)(triphenylphosphine)Cu(tetrahydroborate) 
• 67-56-1 methanol 
• 75-15-0 carbon disulfide 
• 114487-18-2 {(1,10-phenanthroline)2Cu}(formate) 
• 292850-64-7 {(1,10-phenanthroline)2Cu}{B(C₆H₅)4} 
• 32474-61-6 (1,10-phenanthroline)(triphenylphosphine)Cu(formate) 
• 114502-36-2 (1,10-phenanthroline)(triphenylphosphine)Cu(bicarbonate) 

Relevant academic research and scientific papers

Crystallographic and spectroscopic studies of luminescent copper(I) complex [(PPh3)2Cu(S2COMe)] - Insertion reaction of carbon disulfide

The luminescent copper(I) complex [(PPh3)2Cu(S 2COMe)] has been obtained by treating [(PPh3) 2Cu(NO3)] with carbon bisulfide in a mixed solvent of methanol and dichloromethane at room temperature. The complex has been characterized by physico-chemical and spectroscopic methods, and has been found to exhibit photoluminescence behaviour at room temperature. The structure of the complex has been determined by X-ray structure analysis. The crystal is orthorhombic, space group P212121, with parameters a = 9.513(2) A, b = 18.075(4) A, c = 19.968 A, V = 3433.4(12) A3, Z = 4, F(000) = 1440, D(calcd) = 1.345 Mg/m3, μ = 0.880 mm-1, R = 0.0487, Rw = 0.0935. The results show that PPh3 coordinates as monodentate ligand to the copper(I) atoms, and MeCOS2- behaves as a bidentate ligand in the prepared complex. Hence, each copper atom has a CuP 2S2 tetrahedron coordination skeleton.