65037-30-1Relevant academic research and scientific papers
Preparation method and device for iodobenzene dibenzoate derivative
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Paragraph 0032; 0033; 0034; 0035, (2017/02/09)
The invention relates to a preparation method and device for an iodobenzene dibenzoate derivative. The method includes the steps that 6 mmol of iodobenzene diacetate and 12 mmol of benzoic acid or a benzoic acid derivative or pivalic acid are added into a
Palladium catalyzed ortho-C-H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates
Zhang, Qian,Wang, Ying,Yang, Tingting,Li, Li,Li, Dong
supporting information, p. 6136 - 6141 (2015/10/28)
A palladium-catalyzed ortho-C-H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates has been developed. The reaction employed the stable and easily accessible hypervalent iodine reagents as both benzoxylate source and oxidant which made the protocol simple and facile. It showed high regioselectivity and good functional group tolerance, and gave the mono-benzoxylation products in moderate to excellent yields.
α-Acyloxynitroso dienophiles in [4+2] hetero Diels-Alder cycloadditions: mechanistic insights
Calvet, Géraldine,Coote, Susannah C.,Blanchard, Nicolas,Kouklovsky, Cyrille
supporting information; experimental part, p. 2969 - 2980 (2010/06/20)
α-Acyloxynitroso derivatives are a class of heterodienophiles leading to valuable 3,6-dihydro-1,2-oxazines or the corresponding aminoalcohols in good yields. The discovery that a β-oxygenated moiety led to a domino [4+2] cycloaddition/σN-O bond cleavage in the presence of a catalytic amount of Lewis acid was investigated in detail, through kinetic profiling of the reaction both in the absence and presence of a promoter. These studies showed that the role of the Lewis acid was to accelerate the σN-O bond cleavage thereby promoting a highly reproducible sequence. In addition, our preliminary results on an asymmetric version of this domino sequence are reported.
MERCURY MEDIATED SYNTHESIS OF BIS(CARBOXY)IODOBENZENES
Taylor, Richard T.,Stevenson, Thomas A.
, p. 2033 - 2036 (2007/10/02)
Iodobenzene dibenzoates and acetoxylates can be conveniently prepared from iodobenzene dichloride and the corresponding mercuric carboxylate generated in situ.Especially noteworthy is the high yield preparation of bis(trifluoroacetoxy)iodobenzene.
