65103-37-9

Upstream product

• 100-47-0 benzonitrile 
• 18039-42-4 5-Phenyl-1H-tetrazole 
• 35466-83-2 allyl methyl carbonate 
• 106-95-6 allyl bromide 

Downstream Products

• 18039-42-4 5-Phenyl-1H-tetrazole 

Relevant academic research and scientific papers

Crystal structure of a π complex of AgBF4 with 2-allyl-5-phenyl-2H-tetrazole of the composition [Ag(C10H10N4)(BF4)]

By the interaction of AgBF4 with 2-allyl-5-phenyl-2H-tetrazole (2aphet) in the ethanol solution, a π complex of [Ag(2aphet)(BF4)] is obtained which is studied using single crystal X-ray diffraction.

Sustainable Palladium-Catalyzed Tsuji-Trost Reactions Enabled by Aqueous Micellar Catalysis

Palladium-catalyzed allylic substitution, or "Tsuji-Trost"reactions, can be run under micellar catalysis conditions featuring not only chemistry in water but also numerous combinations of reaction partners that require low levels of palladium, typically on the order of 1000 ppm (0.1 mol %). These couplings are further characterized by especially mild conditions, leading to a number of cases not previously reported in an aqueous micellar medium. Inclusion of diverse nucleophiles, such as N-H heterocycles, alcohols, dicarbonyl compounds, and sulfonamides is described. Intramolecular cyclizations further illustrate the broad utility of this process. In addition to recycling studies, a multigram scale example is reported, indicative of the prospects for scale up.

Exothermic or Endothermic Decomposition of Disubstituted Tetrazoles Tuned by Substitution Fashion and Substituents

Nitrogen-rich compounds such as tetrazoles are widely used as candidates in gas-generating agents. However, the details of the differentiation of the two isomers of disubstituted tetrazoles are rarely studied, which is very important information for designing advanced materials based on tetrazoles. In this article, pairs of 2,5- and 1,5-disubstituted tetrazoles were carefully designed and prepared for study on their thermal decomposition behavior. Also, the substitution fashion of 2,5- and 1,5- and the substituents at C-5 position were found to affect the endothermic or exothermic properties. This is for the first time to the best of our knowledge that the thermal decomposition properties of different tetrazoles could be tuned by substitution ways and substitute groups, which could be used as a useful platform to design advanced materials for temperature-dependent rockets. The aza-Claisen rearrangement was proposed to understand the endothermic decomposition behavior.