65127-37-9

Basic information

• Product Name: 2-Propenoic acid, 2-methyl-3,3-diphenyl-, ethyl ester
• CAS NO: 65127-37-9
• Molecular Formula: C18H18O2
• Molecular Weight: 266.34
• Mol File: 65127-37-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-methyl-3,3-diphenyl-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-methyl-3,3-diphenyl-, ethyl ester(65127-37-9)
• EPA Substance Registry System: 2-Propenoic acid, 2-methyl-3,3-diphenyl-, ethyl ester(65127-37-9)

Safety Data

• Hazardous Substances Data: 65127-37-9(Hazardous Substances Data)

Upstream product

• 58473-62-4 ethyl 3-hydroxy-2-methyl-3,3-diphenylpropionate 
• 71-43-2 benzene 
• 86119-84-8 phosphoric acid 
• 17792-17-5 ethyl 3,3-diphenylacrylate 
• 74-88-4 methyl iodide 
• 86108-39-6 2-Methyl-2,3-diphenyl-3-(toluene-4-sulfonyloxy)-propionic acid ethyl ester 

Downstream Products

• 5292-20-6 α-methyl-β,β-diphenylpropionic acid 
• 13304-52-4 2-methyl-3-phenylinden-1-one 
• 65127-36-8 ethyl 2-(bromomethyl)-3,3-diphenylacrylate 
• 102156-38-7 2-dimethylaminomethyl-3,3-diphenyl-acrylic acid ethyl ester 
• 102663-58-1 2-morpholinomethyl-3,3-diphenyl-acrylic acid ethyl ester 
• 17684-12-7 2-methyl-3,3-diphenyl-2-propenoic acid 

Relevant articles and documents

AN INTERPRETATION OF THE SUBSTITUENT EFFECT IN THE BLAISE REARRANGEMENT IN TERMS OF PI-ORBITALS

The migratory aptitude of the substituent groups in the Blaise rearrangement can be explained in terms of the pi-electronic properties of the groups in the highest occupied molecular orbitals.The rates of the rearrangement reaction with relation to the substituent groups were also rationally understood based on the energy levels of the molecular orbitals.