65127-37-9Relevant articles and documents
AN INTERPRETATION OF THE SUBSTITUENT EFFECT IN THE BLAISE REARRANGEMENT IN TERMS OF PI-ORBITALS
Abe, Yukio,Suehiro, Tadashi
, p. 389 - 392 (2007/10/02)
The migratory aptitude of the substituent groups in the Blaise rearrangement can be explained in terms of the pi-electronic properties of the groups in the highest occupied molecular orbitals.The rates of the rearrangement reaction with relation to the substituent groups were also rationally understood based on the energy levels of the molecular orbitals.
Vinyl Anions. Part 9. Vinyl Carbanions Derived from Acrylic Esters and their β-Phenyl Derivatives
Feit, Ben Ami,Melamed, Uri,Schmidt, Richard R.,Speer, Heike
, p. 1329 - 1338 (2007/10/02)
Ethyl ββ-diphenylacrylate, ethyl cis- and trans-cinnamate, methyl and ethyl maleate, ethyl fumarate, and methyl acrylate were treated with a strong base at low temperatures to yield the derived vinyl carbanions.The vinyl carbanions were treated with vario