652993-93-6

Upstream product

• 537031-63-3 (E)-1-(2'-N-acetylamino-3',4',6'-tri-O-benzyl-2'-deoxy-α-D-glucopyranosyl)-2-propene 
• 180778-36-3 3-(2'-acetamido-3',4',6-tri-O-acetyl-2'-deoxy-α-D-glucopyranosyl)-1-propene 
• 262286-48-6 3-(2'-N-acetylamino-3',4',6'-tri-O-benzyl-2'-deoxy-α-D-glucopyranosyl)-1-propene 
• 214193-76-7 1-(2'-acetamido-2'-deoxy-α-D-glucopyranosyl)-2-propene 

Downstream Products

• 652993-98-1 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-gulo-heptitol 
• 652993-95-8 (3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-heptitol-1-yl) dibenzyl phosphate 
• 260551-09-5 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-heptonic acid methyl ester 
• 182618-25-3 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-gulo-heptonic acid 
• 260551-11-9 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-1-hydroxy-D-glycero-D-ido-heptitol 
• 652993-94-7 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-aldehydo-D-glycero-D-gulo-heptose 
• 260551-08-4 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-heptonic acid 

Relevant academic research and scientific papers

Synthesis of α- and β-C-glycosides of N-acetylglucosamine

As part of efforts to make available new classes of bioactive C-glycoconjugates, D-glucosamine has been effectively converted into a series of 2-deoxy-2-amino-C-glycosides. This versatile approach is keyed by a remarkably effective metal catalyzed olefin isomerization of the isomeric C-allyl amino sugars which, in turn, are readily available via radical allylation of D-glucosamine.

Synthesis of C-Glycosyl Phosphate and Phosphonate, Analogues of N-Acetyl-α-D-Glucosamine 1-Phosphate

Synthesis of α-C-ethylene phosphate and phosphonate as well as α-C-methylene phosphate analogues of N-acetyl-α-D-glucosamine 1-phosphate is reported starting from the common perbenzylated 2-acetamido-2-deoxy-α-C-allyl glucoside. Anomerisation of the corre