1226-39-7

Basic information

• Product Name: 4-NITROPHENYL-BETA-D-FUCOPYRANOSIDE
• Synonyms: 4-NITROPHENYL-BETA-D-FUCOPYRANOSIDE;4-NITROPHENYL-BETA-D-FUCOSE;P-NITROPHENYL BETA-D-FUCOPYRANOSIDE;P-NITROPHENYL-BETA-D-FUCOSIDE;P-NITROPHENYL-ALPHA-D-FUCOSIDE;PNP-BETA-D-FUC;P-NITROPHENYL B-D-FUCOPYRANOSIDE;4-nitrophenyl β-d-fuco-pyran-oside
• CAS NO: 1226-39-7
• Molecular Formula: C₁₂H₁₅NO₇
• Molecular Weight: 285.25
• EINECS: 1533716-785-6
• Product Categories: Sugars, Carbohydrates & Glucosides;Biochemistry;Fucose;Glycosides;Sugars;Enzyme Substrates;Fucosidase, alpha-L-;Glycosidase, beta;ChromogenicEnzyme Substrates;Fucoside;Substrates;Substrates by Enzyme;substrate
• Mol File: 1226-39-7.mol
• Article Data: 3

Chemical Properties

• Melting Point: 191-192 °C
• Boiling Point: 515.4oC at 760 mmHg
• Flash Point: 265.5oC
• Appearance: /
• Density: 1.503g/cm3
• Vapor Pressure: 1.9E-11mmHg at 25°C
• Refractive Index: -75 ° (C=1, EtOH)
• Storage Temp.: −20°C
• PKA: 12.68±0.70(Predicted)
• BRN: 1291394
• CAS DataBase Reference: 4-NITROPHENYL-BETA-D-FUCOPYRANOSIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-NITROPHENYL-BETA-D-FUCOPYRANOSIDE(1226-39-7)
• EPA Substance Registry System: 4-NITROPHENYL-BETA-D-FUCOPYRANOSIDE(1226-39-7)

Safety Data

• Safety Statements: 24/25
• WGK Germany: 3
• F: 10
• Hazardous Substances Data: 1226-39-7(Hazardous Substances Data)

Usage

Uses

4-Nitrophenyl beta-D-Fucopyranoside (cas# 1226-39-7) is a compound useful in organic synthesis.

InChI:InChI=1/C12H15NO7/c1-6-9(14)10(15)11(16)12(19-6)20-8-4-2-7(3-5-8)13(17)18/h2-6,9-12,14-16H,1H3/t6-,9+,10+,11-,12+/m1/s1

Upstream product

• 84729-97-5 p-nitrophenyl 2,3,4-tri-O-acetyl-β-D-fucopyranoside 
• 73-34-7 D-Fucose 
• 51921-33-6 1,2,3,4-tetra-O-acetyl-D-fucopyranose 
• 5158-64-5 2,3,4-tri-O-acetyl-D-fucopyranosyl bromide 
• 100-02-7 4-nitro-phenol 
• 5160-09-8 2,3,4‐tri‐O‐acetyl-α-L‐rhamnopyranosyl chloride 
• 18992-37-5 4-nitrophenyl-2,3,4,6-tetra-O-acetyl-α-L-rhamnopyranoside 
• 824-78-2 4-nitrophenol sodium salt 

Downstream Products

• 183878-99-1 1-(4-aminophenoxy)-α-L-rhamnopyranoside 
• 100-02-7 4-nitro-phenol 
• 73-34-7 D-Fucose 
• 26255-70-9 4-nitrophenyl β-D-glucopyranosyl-(1->3)-β-D-glucopyranoside 
• 2713-54-4 α-D-mannopyranosyl fluoride 
• 1604814-89-2 p-nitrophenyl β-D-galactofuranosyl-(1→4)-α-L-rhamnopyranoside 
• 51885-04-2 p-aminophenyl-β-D-thiofucopyranoside 
• 88-75-5 2-hydroxynitrobenzene 
• 6014-42-2 L-rhamnose 
• 3615-41-6 L-Rhamnose 
• 1402245-81-1 C₁₈H₂₅NO₁₂ 
• 342627-40-1 p-nitrophenyl β-D-fucopyranosyl-(1,3)-β-D-fucopyranoside 
• 1373921-67-5 β-D-Fuc-(1->4)-β-D-Glc-(1->3)-β-D-Fuc-pNP 

Relevant articles and documents

Synthesis of aryl α-O-L-rhamnopyranoside by two-step reaction in one pot

The title compounds were conveniently synthesized by a phase transfer catalyzed approach in two steps and one pot using the rhamnopyranosyl chloride as key intermediate. The twostep one-pot procedure is more convenient and environmentally friendly, compared to the published synthetic routes. Besides, the structure-reactivity relationship and the plausible mechanism for this base-catalyzed glycosylation were discussed bymeans of the Hammett equation.

Synthesis of p-nitrophenyl 2-O-alpha- and -beta-L-fucopyranosyl-beta-D-fucopyranoside.

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