65480-93-5Relevant academic research and scientific papers
α-CYCLIZATION OF TERTIARY AMINES. PART 2. VIA (2+2) CYCLOADDITION OF β-AMINOACRYLONITRILES WITH ACETYLENEDICARBOXYLATE
Jiang, Shuiping,Janousek, Zdenek,Viehe, Heinz G.
, p. 663 - 668 (2007/10/02)
The reaction of β-tert.-aminoacrylonitriles 1a-1c with dimethyl acetylenedicarboxylate (DMAD) to give pyrrolizidine, indolizidine and pyrroloazepine is described.
Arylazide additions to α- and β- aminoacrylonitriles: Synthesis of 5-amino and 4-cyano-1,2,3-triazoles. Kinetic study of the cycloaddition
Derdour, A.,Benabdallah, T.,Merah, B.,Texier, F.
, p. 69 - 78 (2007/10/02)
Arylazides reacted with α-aminoacrylonitriles 1 (captodative olefins) to produce in excellant yields 5-amino-1-aryl-1,2,3-triazoles.HCN was spontaneously eliminated from the corresponding triazoline.Reaction of the same 1,3-dipoles with β-aminoacrylonitri
NUCLEOPHILIC ADDITIONS TO α,β-UNSATURATED SULPHONES. III. REGIOCHEMISTRY OF THE REACTION OF (E)-β-CYANOVINYL PHENYL SULPHONE WITH NITROGEN, OXYGEN AND CARBON NUCLEOPHILES
Benedetti, Fabio,Fabrissin, Silvio,Pricl, Sabrina,Risaliti, Amerigo
, p. 391 - 394 (2007/10/02)
The reactions of the title compound with secondary amines, alcohols, and enamines have been studied.Addition or addition-elimination at either electrophilic position is observed.Regiochemistry is a function of steric and electronic effects and of electrostatic interactions.
A One Pot Synthesis of β-Cyanoenamines
Rene, Loic,Poncet, Joeel,Auzou, Gilles
, p. 419 - 420 (2007/10/02)
Orthoesters, cyanoacetic acid and secondary amines react together, in a one step procedure, to produce β-cyanoenamines.
