6553-81-7

Basic information

• Product Name: butyl cyclohexanecarboxylate
• Synonyms: butyl cyclohexanecarboxylate;CYCLOHEXANECARBOXYLIC ACID, BUTYL ESTER;N-BUTYL CYCLOHEXANECARBOXYLATE;Ai3-33528;Einecs 229-475-4
• CAS NO: 6553-81-7
• Molecular Formula: C₁₁H₂₀O₂
• Molecular Weight: 184.2753
• EINECS: 229-475-4
• Mol File: 6553-81-7.mol
• Article Data: 26

Chemical Properties

• Boiling Point: 232.2°Cat760mmHg
• Flash Point: 87.1°C
• Appearance: /
• Density: 0.951g/cm³
• Vapor Pressure: 0.0599mmHg at 25°C
• Refractive Index: 1.454
• CAS DataBase Reference: butyl cyclohexanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: butyl cyclohexanecarboxylate(6553-81-7)
• EPA Substance Registry System: butyl cyclohexanecarboxylate(6553-81-7)

Safety Data

• Hazardous Substances Data: 6553-81-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H20O2/c1-2-3-9-13-11(12)10-7-5-4-6-8-10/h10H,2-9H2,1H3

Upstream product

• 71-36-3 butan-1-ol 
• 98-89-5 Cyclohexanecarboxylic acid 
• 2043-61-0 cyclohexanecarbaldehyde 
• 141-32-2 acrylic acid n-butyl ester 
• 7789-67-5 stannic bromide 
• 4630-82-4 methyl cyclohexylcarboxylate 
• 201230-82-2 carbon monoxide 
• 108-85-0 1-bromocyclohexane 
• 110-82-7 cyclohexane 
• 766-05-2 cyclohexane carbonitrile 
• 1122-56-1 cyclohexylcarboxamide 
• 37170-50-6 di(methyl)tert-butyl(n-butoxy)silane 
• 6830-84-8 N-methylcyclohexanecarboxamide 
• 23054-48-0 N-(2-hydroxyethyl)cyclohexanecarboxamide 

Relevant articles and documents

Zr-MOF-808 as Catalyst for Amide Esterification

In this work, zirconium-based metal–organic framework Zr-MOF-808-P has been found to be an efficient and versatile catalyst for amide esterification. Comparing with previously reported homogeneous and heterogeneous catalysts, Zr-MOF-808-P can promote the reaction for a wide range of primary, secondary and tertiary amides with n-butanol as nucleophilic agent. Different alcohols have been employed in amide esterification with quantitative yields. Moreover, the catalyst acts as a heterogeneous catalyst and could be reused for at least five consecutive cycles. The amide esterification mechanism has been studied on the Zr-MOF-808 at molecular level by in situ FTIR spectroscopic technique and kinetic study.

Cobalt-Nanoparticles Catalyzed Efficient and Selective Hydrogenation of Aromatic Hydrocarbons

The development of inexpensive and practical catalysts for arene hydrogenations is key for future valorizations of this general feedstock. Here, we report the development of cobalt nanoparticles supported on silica as selective and general catalysts for such reactions. The specific nanoparticles were prepared by assembling cobalt-pyromellitic acid-piperazine coordination polymer on commercial silica and subsequent pyrolysis. Applying the optimal nanocatalyst, industrial bulk, substituted, and functionalized arenes as well as polycyclic aromatic hydrocarbons are selectively hydrogenated to obtain cyclohexane-based compounds under industrially viable and scalable conditions. The applicability of this hydrogenation methodology is presented for the storage of H2 in liquid organic hydrogen carriers.

Copper-Catalyzed Alkoxycarbonylation of Alkanes with Alcohols

Esters are important chemicals widely used in various areas, and alkoxycarbonylation represents one of the most powerful tools for their synthesis. In this communication, a new copper-catalyzed carbonylative procedure for the synthesis of aliphatic esters from cycloalkanes and alcohols was developed. Through direct activation of the C sp3 ?H bond of alkanes and with alcohols as the nucleophiles, the desired esters were prepared in moderate-to-good yields. Paraformaldehyde could also be applied for in situ alcohol generation by radical trapping, and moderate yields of the corresponding esters could be produced. Notably, this is the first report on copper-catalyzed alkoxycarbonylation of alkanes.