65756-04-9

Upstream product

• 20377-80-4 (+/-)-trans-2-chlorocyclopentanol 
• 930-69-8 sodium thiophenolate 
• 285-67-6 Cyclopentene oxide 
• 13865-50-4 methoxymethyl phenyl sulfide 
• 285-67-6 (1S,5R)-6-Oxa-bicyclo[3.1.0]hexane 
• 108-98-5 thiophenol 
• 142-29-0 cyclopentene 
• 2973-86-6 lithium thiophenoxide 
• 110-87-2 3,4-dihydro-2H-pyran 
• 754201-16-6 N-methoxy-N-methyl-2-(phenylthio)pent-4-enamide 
• 81912-04-1 ethyl 2-(phenylsulfanyl)pent-4-enoate 
• 82777-33-1 5-(phenylthio)pentyl acetate 
• 882-33-7 diphenyldisulfane 
• 83711-12-0 5,5-bis(phenylthio)-1-pentanol 

Downstream Products

• 68771-14-2 Acetic acid 5-oxo-1-phenylsulfanyl-pentyl ester 
• 77520-16-2 (1S,2S)-2-phenylthio-1-cyclopentanol 
• 154617-12-6 (1R, 2R)-2-(phenylthio)cyclopentyl acetate 
• 1229238-98-5 C₁₈H₁₈O₂S 
• 1200400-54-9 (1R,2R)-2-phenylthio-1-cyclopentanol 
• 109667-02-9 (R)-2-cyclopentenyl acetate 
• 74532-80-2 2-(phenylsulfonyl)cyclopentanone 

Relevant academic research and scientific papers

Dual Activation of Unsaturated Amides with Schwartz's Reagent: A Diastereoselective Access to Cyclopentanols and N,O-Dimethylcyclopentylhydroxylamines.

The diastereoselective access to cyclopentanols and N,O-dimethylcyclopentylhydroxylamines from 4-pentenoic acid-derived Weinreb amides is described. Based on the concomitant generation of both the nucleophilic and the electrophilic poles by hydrozirconati

Lithium BINOL phosphate catalyzed desymmetrization of meso-epoxides with aromatic thiols

A highly enantioselective method for desymmetrization of meso-epoxides using thiols is reported. This is the first example of epoxide activation achieved using metal BINOL phosphates. The reaction has a broad scope in terms of epoxide substrates and aroma

Highly enantioselective kinetic resolution of trans-2-(phenylthio) cyclohexanol derivatives by immobilized Candida antartica B lipase

Candida antartica B (immobilized CAL-B) mediated resolutions of trans-2-(phenylthio)cyclohexanol derivatives using vinyl acetate as acylating agent and MTBE as solvent provide excellent enantioselectivity (up to >99%) and high yield of both the enantiomer

Borax-catalyzed thiolysis of 1,2-epoxides in aqueous medium

A convenient, economical, and practical protocol for borax-catalyzed thiolysis of 1,2-epoxides in aqueous medium has been developed, which has greatly expanded the utility scope of borax in organic synthesis.

Enantioselective ring-opening reaction of meso-epoxides with ArSH catalyzed by a C2-symmetric chiral bipyridyldiol-titanium complex

This study describes a C2-symmetric ligand comprising a central bipyridine-pinene-derived core and two functionalized diphenylmethanol subunits. [8′-(Hydroxy-diphenyl-methyl)-10,10,10′,10′-tetramethy l-[5,5′]bi[6-aza-tricyclo[7.1.1.02,7/s

Thiolysis of 1,2-epoxides by thiophenol catalyzed under solvent-free conditions

Thiolysis of alkyl- and aryl-1,2-epoxides was investigated under solvent-free conditions in the presence of Lewis and Br?nsted acid and base catalysts (InCl3, p-TsOH, n-Bu3P, K2CO3). Five mol% of catalyst was su

Efficient ring-opening reaction of epoxides and aziridines promoted by tributylphosphine in water

Tributylphosphine was found to be an effective promoting reagent for the ring-opening reaction of various epoxides and aziridines with nucleophile to produce corresponding anti-bifunctional products in moderate to excellent yields in water.

Highly efficient cleavage of epoxides catalyzed by B(C6F5)3

A highly effective protocol for ring opening of epoxides with allyl and propargyl alcohols, aniline and thiophenol in the presence of catalytic amounts of B(C6F5)3 has been developed. Benzyl, tetrahydropyranyl, tert-butyld

InCl3-catalyzed highly regioselective ring opening of epoxides with thiols

Epoxides react smoothly with thiols in the presence of 10 mol% InCl3 under very mild conditions to afford the corresponding β-hydroxy sulfides in high yields with high regioselectivity. Similar yields and selectivity are also obtained with cata

Tetrathiomolybdate assisted epoxide ring opening with masked thiolates and selenoates: Multistep reactions in one pot

Tetrathiomolybdate provides an easy access to β-hydroxy disulfides, β-hydroxy sulfides, and selenides from epoxides in a tandem, multistep process in one pot. This strategy has been utilized effectively in the construction of thiabicylo[3.2.2]nonane derivative 24.