65899-10-7

Basic information

• Product Name: Silane, 1,2-ethenediylbis[dichloromethyl-, (E)-
• CAS NO: 65899-10-7
• Molecular Formula: C4H8Cl4Si2
• Molecular Weight: 254.091
• Mol File: 65899-10-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Silane, 1,2-ethenediylbis[dichloromethyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, 1,2-ethenediylbis[dichloromethyl-, (E)-(65899-10-7)
• EPA Substance Registry System: Silane, 1,2-ethenediylbis[dichloromethyl-, (E)-(65899-10-7)

Safety Data

• Hazardous Substances Data: 65899-10-7(Hazardous Substances Data)

Upstream product

• 75-54-7 Dichloromethylsilane 
• 74-86-2 acetylene 
• 4518-98-3 1,1,2,2-tetrachloro-1,2-dimethyldisilane 
• 116-15-4 perfluoropropylene 
• 124-70-9 Dichloromethylvinylsilane 
• 14015-32-8 ethynylmethyldichlorosilane 
• 156-60-5 trans-1,2-dichloroethylene 
• 156-59-2 cis-1,2-Dichloroethylene 

Relevant articles and documents

PALLADIUM COMPLEXES IN THE HYDROSILYLATION OF ACETYLENE

The catalytic activities of triphenylphosphine-, trialkylphosphine-, and acetylacetone-palladium complexes in the hydrosilylation of acetylene with trichloro-, alkyldichloro-, triethyl, and triethoxy-silanes were investigated.The yields of the corresponding (triorganylsilyl)ethylenes and 1,2-bis(triorganylsilyl)ethanes (conditions: 70-80 deg C, solvent xylene) depend on the nature of the ligands on the palladium atom and the character of the substituents on the silicon atom in the hydride silane.

ETHYLENE DERIVATIVES IN CYCLOADITION REACTIONS OF FLUORO-ALKENES AND -ALKANES

-

ADDITION OF CHLORODISILANES TO ACETYLENE CATALYZED BY TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0). A FACILE ROUTE TO (Z)-1,2-BIS(CHLOROSILYL)ETHENES

In the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0), chlorodisilanes of type MenSi2Cl6-n (n=2-5) add to acetylene to afford 1,2-bis(chlorosilyl)ethenes in reasonable yields.