6591-42-0Relevant academic research and scientific papers
Intramolecular nucleophilic substitution of ω-haloalkylphosphine derivatives
Pawe?, Wo?nicki,Korzeniowska, Ewelina,Stankevic, Marek
, p. 10271 - 10296 (2018/02/27)
ω-Haloalkylphosphine derivatives undergo the intramolecular nucleophilic substitution reaction upon treatment with a strong base, yielding either cycloalkylphosphine derivatives or heterocyclic phosphine derivatives. The selectivity of the cyclization of
Facile non-catalyzed synthesis of tertiary phosphine sulfides by regioselective addition of secondary phosphine sulfides to alkenes
Malysheva, Svetlana F.,Gusarova, Nina K.,Artem'Ev, Alexander V.,Belogorlova, Nataliya A.,Albanov, Alexander I.,Borodina, Tatyana N.,Smirnov, Vladimir I.,Trofimov, Boris A.
, p. 2516 - 2521 (2014/05/06)
An atom-economic green synthesis of tertiary phsophine sulfides has been developed based on catalyst- and solvent-free addition of secondary phosphine sulfides to diverse terminal and internal alkenes (hept-1-ene, cyclohexene, styrenes, allyl alcohol, vin
Radical phosphination of organic halides and alkyl imidazole-1- carbothioates
Sato, Akinori,Yorimitsu, Hideki,Oshima, Koichiro
, p. 4240 - 4241 (2007/10/03)
Taking advantage of a radical-based methodology, mild and chemoselective phosphination reactions of organic halide and alkyl imidazole-1-carbothioates have been developed. The mild reaction conditions allow labile functional groups to survive during the reaction. Copyright
Radical addition reactions of diphenylphosphine sulfide
Parsons, Andrew F.,Sharpe, David J.,Taylor, Philip
, p. 2981 - 2983 (2007/10/03)
Radical additions of diphenylphosphine sulfide [Ph2P(S)H] to various C=C bonds offers a general, mild and efficient approach to alkyl(diphenyl)phosphine sulfides. Georg Thieme Verlag Stuttgart.
Palladium-catalyzed synthesis of vinyl phosphines from ketones
Gilbertson, Scott R.,Fu, Zice,Starkey, Gale W.
, p. 8509 - 8512 (2007/10/03)
The palladium-catalyzed conversion of vinyl triflates to vinyl phosphines is reported. This process allows for the synthesis of vinyl phosphines from ketones. Selective enolization of a variety of ketones followed by trapping of the enolate as the vinyl triflate is reported. The vinyl triflates are then converted to the corresponding vinyl phosphine through palladium catalysis. The resulting vinyl phosphines can then be reduced to give alkyl phosphines.
Conformational Preference of the Diphenylthiophosphinoyl Group in Cyclohexane and in the 1,3-Dithian-2-yl Ring
Juaristi, Eusebio,Lopez-Nunez, Norma A.,Valenzuela, Bertha A.,Valle, Lucia,Toscano, Ruben A.,Soriano-Garcia, Manuel
, p. 5184 - 5189 (2007/10/02)
The conformational energy (A value) of the diphenylthiophosphinoyl group in cyclohexane was determined from the incorporation of 13C NMR data of mobile cis-4-(diphenylthiophosphinoyl)-1-phenylcyclohexane (4) and conformationally fixed cis- (5) and trans-4
