66003-63-2Relevant articles and documents
CATALYTIC CARBOXYLATION OF ACTIVATED ALKANES AND/OR OLEFINS
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Page/Page column 64; 65, (2018/02/28)
The present invention relates to a method of reacting starting materials with an activating group, namely alkanes carrying a leaving group and/or olefins, with carbon dioxide under transition metal catalysis to give carboxyl group-containing products. It is a special feature of the method of the present invention that the carboxylation predominantly takes place at a preferred position of the molecule irrespective of the position of the activating group. The carboxylation position is either an aliphatic terminus of the molecule or it is a carbon atom adjacent to a carbon carrying an electron withdrawing group. The course of the reaction can be controlled by appropriately choosing the reaction conditions to yield the desired regioisomer.
Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water
Gaydou, Morgane,Moragas, Toni,Juliá-Hernández, Francisco,Martin, Ruben
supporting information, p. 12161 - 12164 (2017/09/12)
A catalytic protocol that reliably predicts and controls the site-selective incorporation of CO2 to a wide range of unsaturated hydrocarbons utilizing water as formal hydride source is described. This platform unlocks an opportunity to catalytically repurpose three abundant, orthogonal feedstocks under mild conditions.
FUNCTIONALISED NANOPARTICLES, THEIR PRODUCTION AND USE
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Page/Page column 11, (2012/07/27)
Stable complexes are described, formed by mono- and di-functional compounds bound to nanoparticles composed of various types of transition metal oxides and of metals useful in the production processes of different types of new materials (such as for examp
