661-68-7Relevant academic research and scientific papers
Photoinduced electron-transfer reaction of 7,8- disilabicyclo[2.2.2]octa-2,5-dienes
Kako,Hatakenaka,Kakuma,Ninomiya,Nakadaira,Yasui,Iwasaki,Wakasa,Hayashi
, p. 1133 - 1136 (2007/10/03)
9,10-Dicyanoanthracene-sensitized irradiation of 7,8- disilabicyclo[2.2.2]octa-2-5-dienes1-3 in the presence of MeOH resulted in the formation of dimethoxydisilanes and the corresponding aromatic compounds. A stepwise mechanism involving C-Si bond cleavage by MeOH is proposed.
Preparative electrochemical oxidation of cyclic peralkylsilanes
Becker,Shakkour,West
, p. 5633 - 5636 (2007/10/02)
The electrochemical oxidation of cyclic peralkylsilanes undergo ring opening followed by further Si-Si bond cleavage and reaction with BF4- to form α,ω-difluorosilanes, F-(SiR2)(n)-F, as major products.
