62257-76-5Relevant articles and documents
Highly regioselective rhenium-catalyzed hydrosilylation of styrenes
Zhao, Wen-Guo,Hua, Ruimao
, p. 5495 - 5498 (2006)
The addition reaction of silanes to styrenes is efficiently catalyzed by ReBr(CO)5 in toluene heated at 120°C and selectively affords anti-Markovnikov adducts in good to high yields. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
The two faces of platinum hydrospirophosphorane complexes—Not only relevant catalysts but cytotoxic compounds as well
Skar?yńska, Anna,Kowalczyk, Marta,Majchrzak, Mariusz,Pi?tka, Marta,Augustyniak, Adam W.,Siczek, Mi?osz,W?odarczyk, Kinga,Simiczyjew, Aleksandra,Nowak, Dorota
, (2021/12/08)
Platinum complexes [PtCl2(L)] L = L1, L2 with symmetrical HP (OCH2CMe2NH)2 (L1) and unsymmetrical HP(OCMe2CMe2O)(OCH2CMe2NH) (L2) hydrospirophosphorane (HSP) ligands were demonstrated to play a dual role of catalysts and cytotoxic compounds as well. The structure of new complex [PtCl2(L2)] was confirmed by physicochemical and spectroscopic methods, as well as single X-ray diffraction studies for [PtCl2{P (OCMe2CMe2O)(OCH2CMe2NH2)}]. HSP ligand coordinated to the platinum center in bidentate κ2-P,NH2 chelating mode of fashion. Both complexes were found to exhibit catalytic activity for Heck cross-coupling reactions of iodobenzene with substituted styrenes, with good conversion and yield of stilbenes. Moreover, complexes have been applied as excellent catalysts for highly regioselective hydrosilylation of aromatic and aliphatic terminal olefins, and acetylenes terminal and internal as well. On the other hand, the preliminary biological studies revealed that in the presence of foretinib, drug candidate in clinical trials for the treatment of cancer, platinum complexes revealed increased synergistic effect and efficiently decreased the number of viable cells of triple negative breast cancer MDA-MB-231 cell line.
Catalytic hydrosilylation of olefins and ketones by base metal complexes bearing a 2,2′:6′,2″-terpyridine ancillary ligand
Kobayashi, Katsuaki,Nakazawa, Hiroshi
, (2021/06/12)
The activities of [M(tpy)Br2] (M = Mn, Co, Ni, or Cu) for the hydrosilylation of olefins and ketones were investigated in the presence of NaBHEt3 as an activator. [Co(tpy)Br2] and [Ni(tpy)Br2] showed catalytic a
Accelerated Anti-Markovnikov Alkene Hydrosilylation with Humic-Acid-Supported Electron-Deficient Platinum Single Atoms
Antonietti, Markus,Badamdorj, Bolortuya,Janik, Michael J.,Liu, Kairui,Yang, Fan
supporting information, p. 24220 - 24226 (2021/10/07)
The hydrosilylation reaction is one of the largest-scale applications of homogeneous catalysis, and Pt homogeneous catalysts have been widely used in this reaction for the commercial manufacture of silicon products. However, homogeneous Pt catalysts result in considerable problems, such as undesired side reactions, unacceptable catalyst residues and disposable platinum consumption. Here, we synthesized electron-deficient Pt single atoms supported on humic matter (Pt1@AHA_U_400), and the catalyst was used in hydrosilylation reactions, which showed super activity (turnover frequency as high as 3.0×107 h?1) and selectivity (>99 %). Density functional theory calculations reveal that the high performance of the catalyst results from the atomic dispersion of Pt and the electron deficiency of the Pt1 atoms, which is different from conventional Pt nanoscale catalysts. Excellent performance is maintained during recycle experiments, indicating the high stability of the catalyst.
