66164-41-8

Upstream product

• 100-52-7 benzaldehyde 
• 114273-73-3 (3-methoxy-2E-propylidene)triphenylphosphorane 
• 4009-98-7 (methoxymethyl)triphenylphosphonium chloride 
• 104-55-2 3-phenyl-propenal 
• 118554-59-9 4-phenyl-3-butyn-1-ol methyl ether 

Relevant academic research and scientific papers

Isomerization of alkynes to 1,3-dienes under rhodium or palladium catalysis

Treatment of 1-aryl-1-octyne with allyltributylstannane under rhodium catalysis provided 1-aryl-1,3-octadiene in good yield. A combination of ally1 acetate and a palladium catalyst also effected the isomerization of alkynes to 1,3-dienes. Georg Thieme Ver

SYNTHESIS OF VINYL ETHERS BY HOMOLOGATION OF ALDEHYDES VIA RADICAL REDUCTIVE ELIMINATION

Methoxyphenylthiomethyllithium 1 reacts with aldehydes to give adducts which are then transformed into xanthates.These compounds, by reaction with tri-n-butylstannane, afford vinyl ethers in good yields.