6639-86-7

Basic information

• Product Name: 2-METHYLQUINOXALINEDIIUM-1,4-DIOLATE
• Synonyms: Quinoxaline, 2-methyl-, 1,4-dioxide;quinoxaline,2-methyl-,1,4-dioxide;2-METHYLQUINOXALINEDIIUM-1,4-DIOLATE;2-methylquinoxaline 1,4-dioxide;Quinoxaline, 2-methyl-, 1,4-dioxide (6CI,7CI,8CI,9CI);Einecs 229-648-4;Nsc 48949;2-Methylquinoxaline di-N-oxide
• CAS NO: 6639-86-7
• Molecular Formula: C₉H₈N₂O₂
• Molecular Weight: 176.17
• EINECS: 229-648-4
• Product Categories: PIPERIDINE;Intermediates & Fine Chemicals;Nitric Oxide Reagents;Pharmaceuticals
• Mol File: 6639-86-7.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• Storage Temp.: Refrigerator, under inert atmosphere
• Solubility: Chloroform (Slightly), Methanol (Slightly)
• CAS DataBase Reference: 2-METHYLQUINOXALINEDIIUM-1,4-DIOLATE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHYLQUINOXALINEDIIUM-1,4-DIOLATE(6639-86-7)
• EPA Substance Registry System: 2-METHYLQUINOXALINEDIIUM-1,4-DIOLATE(6639-86-7)

Safety Data

• Hazardous Substances Data: 6639-86-7(Hazardous Substances Data)

Usage

Chemical Properties

Yellow Solid

Uses

Quinoxaline derivative. Bactericidal activity.

InChI:InChI=1/C9H8N2O2/c1-7-6-10(12)8-4-2-3-5-9(8)11(7)13/h2-6H,1H3

Upstream product

• 480-96-6 benzofurazan oxide 
• 24309-97-5 N-(2-hydroxyethyl)-3-oxobutanamide 
• 105686-38-2 N,N-Dimethyl-3-(trimethylsilyl)-1-propen-1-amin 
• 67-64-1 acetone 
• 18916-45-5 3-Methylquinoxaline 1-Oxide 
• 123-75-1 pyrrolidine 
• 236092-93-6 benzofuroxane N-oxide 
• 123-38-6 propionaldehyde 
• 6795-30-8 3-methylquinoxaline-2-carboxaldehyde-1,4-di-N-oxide 
• 74200-06-9 3-methyl-1,4-dioxide-quinoxaline-2-carboxylic acid 
• 7251-61-8 2-methylquinoxaline 
• 88-74-4 2-nitro-aniline 
• 1322877-87-1 C₆H₄N₂O₂*C₄₂H₇₀O₃₅ 
• 4202-14-6 dimethyl (2-oxopropyl)phosphonate 

Downstream Products

• 84125-21-3 2-{(E)-2-[5-(4-Chloro-phenyl)-furan-2-yl]-vinyl}-quinoxaline 1,4-dioxide 
• 6804-07-5 carbadox 
• 93222-85-6 2-<(nitrooxy)methyl>quinoxaline 1,4-dioxide 
• 84125-20-2 2-<β-<5-(p-Nitrophenyl)furyl>vinyl>quinoxaline di-N-oxide 
• 84125-18-8 2-<β-(2,4-Dichlorophenyl)vinyl>quinoxaline di-N-oxide 
• 84125-17-7 2-<β-(o-Chlorophenyl)vinyl>quinoxaline di-N-oxide 
• 18080-66-5 2-(bromomethyl)quinoxaline 1,4-dioxide 
• 17626-51-6 1,4-dioxoquinoxaline-2-carboxaldehyde 
• 18916-44-4 2-Methyl-chinoxalin-1-oxid 
• 80765-45-3 2-<α-(phenylglyoxyloyl)phenacylidene>-3-methyl-1H-quinoxaline 4-oxide 
• 80765-49-7 2-phenacylidene-3-methyl-1H-quinoxaline 4-oxide 
• 7251-61-8 2-methylquinoxaline 
• 17357-92-5 3-methylquinoxaline-2-carboxamide 
• 84125-13-3 1-(2,4-Dichloro-phenyl)-2-(1,4-dioxy-quinoxalin-2-yl)-ethanol 

Relevant articles and documents

The metabolism of 2-hydroxymethyl-3-methylquinoxaline-di-N-oxide in the chicken, rat, and dog

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Effective promotion of beirut reaction by-cyclodextrin in water

A mild and highly efficient, environmentally friendly procedure has been developed for the conversion from benzofurazan-N-oxides to quinoxaline di-N-oxides in the presence of-cyclodextrin in water at room temperature with excellent yields. The application of cyclodextrin precludes the use of organic solvent, and the catalyst can be recovered and reused in subsequent reactions with the same catalytic activity. Herein, the Beirut reaction is carried out in the medium of water for the first time. The reaction mechanism was proposed based on the inclusion complexation of-cyclodextrin with benzofurazan-N-oxides which was confirmed by 1H NMR, ultraviolet/visible spectrum, and infrared spectroscopy. Copyright

A new efficient route for the formation of quinoxaline N-oxides and N,N′-dioxides using HOF·CH3CN

HOF·CH3CN, a very efficient oxygen-transfer agent made readily from fluorine and aqueous acetonitrile, was reacted with various quinoxaline derivatives to give the corresponding mono N-oxides and especially the N,N′-dioxides in very good yields under mild conditions and short reaction times.