6657-16-5Relevant academic research and scientific papers
Clay catalysed facile rearrangement of diazoaminobenzene to p-aminoazobenzene
Pitchumani, K.,Venkatachalapathy, C.,Sivasubramanian, S.
, p. 187 - 189 (2007/10/03)
Rearrangement of diazoaminobenzene in the presence of acidic cation-exchanged K10-montmorillonite gives exclusively p-aminoazobenzene at room temperature within three hours.
Transitional-Metal-Activated Organic Compounds, XXXV. - ortho-Alkylation of Aromatic Azo Compounds with Alkyllithium Reagents and Lithium Trimethylferrate(1-)
Kauffmann, Thomas,Jordan, Jan,Sander, Joerg
, p. 153 - 155 (2007/10/02)
Whereas methyllithium reacts with 4-(dimethylamino)-, 4-amino-, and 4-methoxyazobenzene, respectively, by ortho-methylation of the electron-rich phenyl residue of the azo compound, (CH3)3FeLi ortho-methylates the less electron-rich phenyl group of 4-(dimethylamino)azobenzene.A mechanistic rationalization is given for both reaction modes.Key Words: Lithium, organo compounds / Iron, organo compounds / Azo compounds / ortho-Alkylation
Substituted N-phenyl-N'benzoyl ureas and their use as insecticides and acaricides
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, (2008/06/13)
Novel N-phenyl-N'benzoylureas which are useful as insecticides and acaricides.
