66680-84-0

Usage

Uses

Used in the Production of Polyurethane Foam:
CIS-TRI-N-BUTYL(1-PROPENYL)TIN is used as a catalyst in the production of polyurethane foam, contributing to the formation of the foam's structure and improving its properties.
Used in the Production of PVC:
In the PVC industry, CIS-TRI-N-BUTYL(1-PROPENYL)TIN serves as a stabilizer, preventing the degradation of PVC and maintaining its quality during processing.
Used in Antifouling Paints and Coatings:
CIS-TRI-N-BUTYL(1-PROPENYL)TIN is used as a biocide in antifouling paints and coatings, inhibiting the growth of microorganisms and preventing the buildup of marine life on surfaces, such as ship hulls and underwater structures.
Environmental Impact and Restrictions:
Due to the toxicity of CIS-TRI-N-BUTYL(1-PROPENYL)TIN and its potential environmental impact, its use has been restricted in many countries. This has led to the development and adoption of safer alternatives in various industries to minimize the risks associated with this organotin compound.

InChI:InChI=1/3C4H9.C3H5.Sn/c3*1-3-4-2;1-3-2;/h3*1,3-4H2,2H3;1,3H,2H3;/rC15H32Sn/c1-5-9-13-16(12-8-4,14-10-6-2)15-11-7-3/h8,12H,5-7,9-11,13-15H2,1-4H3/b12-8-

Upstream product

• 1461-22-9 tributyltin chloride 
• 4226-01-1 tri-n-butyltin lithium 
• 74-86-2 acetylene 
• 917-54-4 methyllithium 
• 74-88-4 methyl iodide 
• 27262-82-4 tributylstannylmagnesium chloride 
• 123-38-6 propionaldehyde 
• 75-36-5 acetyl chloride 
• 937-63-3 p-Tolyl chlorothionoformate 
• 116064-59-6 1-tributylstannyl-propan-1-ol 
• 590-14-7 1-bromo-1-propene 

Downstream Products

• 91897-80-2 1-(1'-cyclohexenyl)-2-buten-1-one 
• 91897-81-3 (Z)-1-(cyclohexen-1-yl)-2-buten-1-one 
• 91897-84-6 (E)-1-(5,5-dimethyl-1-oxo-cyclohex-2-en-3-yl)-2-buten-1-one 
• 120635-31-6 (7R,8R)-7-phenylacetamido-3-[(Z)-propen-1-yl]-3-cephem-4-carboxylic acid p-methoxybenzyl ester 
• 123-73-9 trans-Crotonaldehyde 
• 15798-64-8 cis-crotonaldehyde 
• 205056-69-5 (E)-methyl 2,4-dibenzyloxy-6-(1-propenyl)benzoate 
• 190790-85-3 (7R,8R)-7-phenylacetamido-3-[propen-1-yl]-3-cephem-4-carboxylic acid p-methoxybenzyl ester 
• 659746-84-6 methyl [6-formyl-2-(methoxyiminomethyl)-3-(prop-1-en-1-yl)phenyloxy]acetate 
• 40341-58-0 (E)-2-(4-methoxyphenyl)-3-methyl-5-(prop-1-enyl)benzo[b]furan 
• 1293370-19-0 3-(4-isopropoxy-3-(prop-1-en-1-yl)phenyl)propan-1ol 
• 1361582-33-3 7-hexyl-5-methyl-1-tosyl-2,3,4,5-tetrahydro-1H-indole 

Relevant academic research and scientific papers

Ynamide Carbopalladation: A Flexible Route to Mono-, Bi- and Tricyclic Azacycles

Bromoenynamides represent precursors to a diversity of azacycles by a cascade sequence of carbopalladation followed by cross-coupling/electrocyclization, or reduction processes. Full details of our investigations into intramolecular ynamide carbopalladation are disclosed, which include the first examples of carbopalladation/cross-coupling reactions using potassium organotrifluoroborate salts; and an understanding of factors influencing the success of these processes, including ring size, and the nature of the coupling partner. Additional mechanistic observations are reported, such as the isolation of triene intermediates for electrocyclization. A variety of hetero-Diels-Alder reactions using the product heterocycles are also described, which provide insight into Diels-Alder regioselectivity.

Stannyl-cupration of Acetylenes and the Reaction of the Intermediate Cuprates with Electrophiles as a Synthesis of Substituted Vinylstannanes

Stannyl-cupration of acetylenes followed by electrophilic attack with a variety of electrophiles gives E-vinylstannanes.These can be used either to form acetylenes, thus achieving overall the addition of an ethynyl group, or to form carbon-carbon bonds in Stille reactions.

The Stannyl-Cupration of Acetylenes and the Reaction of the Intermediate Cuprates with Electrophiles as a Synthesis of Substituted Vinylstannanes

Stannyl-cupration of acetylenes followed by electrophilic attack with a variety of electrophiles gives vinylstannanes.

THERMAL DECOMPOSITION OF ORGANOTIN SULFAMATES: A ONE POT SYNTHESIS OF VINYLTRIBUTYLTIN COMPOUNDS

The preparation of some alkyltributyltin sulfamates is described.Thermal decomposition of these compounds provides a route to vinyltributyltin derivatives.

Process for production of ceophalosporins

Cephalosporin and 1-carba(1-dethia)cephalosporin antibiotics substituted in the 3-position with, inter alia, alkyl, alkenyl and alkynyl, are provided via process comprising conversion of a cephalosporin or 1-carba(1-dethia)-3-cephem substituted in the 3-p

Synthese et thermolyse eclair d'esters α-tributylstanniques

The preparation of some alkyltributyltin acetates and thiocarbonates is described.Flash thermolysis of these compounds at high temperature (600-950 deg C) and under a moderate vacuum, provides a new route to vinyltributyltin derivatives.