6681-70-5Relevant academic research and scientific papers
An insight of the reactions of amines with trichloroisocyanuric acid
De Luca, Lidia,Giacomelli, Giampaolo
, p. 2180 - 2184 (2007/10/03)
The reaction between amines or α-aminoacids with trichloroisocyanuric acid is studied under various conditions: N,N-dichloroamines, nitriles and ketones can be obtained from primary amines, while free aminoacids undergo oxidative decarboxylation to the corresponding nitrile of one less carbon atom.
Asymmetric Nitrogen. 72. Geminal Systems. 46. N-Chlorooxaaziridines: Optical Activation, Absolute Configuration, and Chiroptical Properties
Shustov, G.V.,Varlamov, S.V.,Chervin, I.I.,Aliev, A.E.,Kostyanovsky, R.G.,et al.
, p. 4210 - 4215 (2007/10/02)
The chiroptical properties of N-chlorooxaziridines are reported as derived experimentally and by means of ab initio quantum mechanical calculations.The synthesis and optical resolution of 2-chloro-1-oxa-2-azaspirooctane (1) and the diastereomeric 2-c
Pyrolytic Eliminations from N,N-Dichloro Derivatives of Primary, Secondary, and Tertiary Alkyl Primary Amines
Roberts, John T.,Rittberg, Barry R.,Kovacic, Peter
, p. 4111 - 4115 (2007/10/02)
N,N-Dichloro derivatives of primary, secondary, and tertiary alkyl primary amines are easily converted to elimination products by neat or solution pyrolysis during GLC at 190-280 deg C.Good to excellent yields result.In general, the type of product formed depends on the alkyl group: with primary alkyl, the products are alkenes and nitriles; with secondary, alkenes and chloroimines result; and with tertiary types, alkenes are formed.Mechanistic aspects are treated.
