66879-51-4Relevant academic research and scientific papers
Total Synthesis of (-)-Bacchopetiolone via an Asymmetric Hydroxylative Phenol Dearomatization/[4+2]-Dimerization Cascade Promoted by a Novel Salen-Type Chiral Iodane
Coffinier, Romain,Assal, Mourad El,Peixoto, Philippe A.,Bosset, Cyril,Miqueu, Karinne,Sotiropoulos, Jean-Marc,Pouységu, Laurent,Quideau, Stéphane
, p. 1120 - 1123 (2016/03/15)
The first total and biomimetic synthesis of the natural bis(sesquiterpene) (-)-bacchopetiolone (revised structure) was completed through a highly diastereoselective hydroxylative phenol dearomatization/[4+2]-dimerization cascade conversion of (+)-curcuphe
Facile syntheses of (±)-curcuphenol-(±)-curcudiol-±)- curcuhydroquinone, and (±)-curcuquinone
Du, Zhenting,Li, Yong,Wang, Yin,Ding, Lichun,Gao, Jinming
experimental part, p. 1920 - 1926 (2010/09/09)
The syntheses of (±)-curcuphenol 1, (±)-curcudiol 2, (±)-curcuhydroquinone 3, and (±)-curcuquinone 4 have been achieved. The key steps involved in the syntheses were the Reformatsky reaction and hydrogenation reaction. Copyright
Syntheses of (±)-curcuphenol, (±)-curcudiol and (±)-curcuhydroquinone: A Johnson-Claisen rearrangement approach
Du, Zhen-Ting,Yu, Hong-Rui,Xu, Yan,Song, Qi-Liang,Li, An-Pai
experimental part, p. 399 - 403 (2011/04/22)
The synthesis of (±)-curcuphenol 1, (±)-curcudiol 2, (±)-curcuhydroquinone 3 and (±)-curcuquinone 4 had been achieved, in which the Johnson-Claisen rearrangement was used as key step.
Synthesis of bisabolane sesquiterpenes: A Johnson-Claisen rearrangement approach
Du, Zhen Ting,Yu, Hong Rui,Xu, Yan,Li, Yong,Li, An Pai
scheme or table, p. 813 - 815 (2011/11/12)
Several bisabolane sesquiterpenes, (±)-curcumene, (±)-curcuphenol, (±)-curcudiol and (±)-curcuhydroquinone, have been synthesized in racemic form and fully characterized. The salient characteristic of our approach is that a Johnson-Claisen arrangement was
Efficient total synthesis of racemic bisabolane sesquiterpenes curcuphenol and xanthorrhizol starting from substituted acetophenones
Montiel, Luisa E.,Zepeda, L. Gerardo,Tamariz, Joaquin
experimental part, p. 1261 - 1273 (2010/09/07)
A total synthesis of natural bisabolane sesquiterpenes curcuphenol (1) and xanthorrhizol (2) was developed by using the substituted acetophenones 4 and 5, respectively, as starting materials. The acetyl group of the latter was activated through ethoxycarb
Facile synthesis of (±)-parahigginone methyl ether and (±)-curcuphenol
Du, Zhen-Ting,Li, An-Pai,Peng, Kun,Wu, Tong-Xing,Pan, Xin-Fu
, p. 571 - 574 (2007/10/03)
Using Grinard coupling as a key step, a facile synthetic approach to (±)-parahigginone methyl ether 1 and (±)-curcuphenol 2 has been achieved by five steps with 42.3% and 58.6% overall yield, respectively.
Synthesis of (±) curcuphenol and (±)-β-sesquiphellandrene
Sharma,Chand, Tek
, p. 553 - 556 (2007/10/03)
Two naturally occurring compounds curcuphenol 1 and β-sesquiphellandrene 2 have been synthesised using lithium tetrachlorocuperate catalysed coupling reaction.
Synthesis of phenolic sesquiterpenes via oxidative cleavage of benzocycloalkenols
Ho, Tse-Lok,Yang, Po-Fei
, p. 181 - 192 (2007/10/02)
Phenolic sesquiterpenes including sesquichamaenol, 6-(2-hydroxy-4-methylphenyl)-2-methyl-3-heptanone, and curcuphenol methyl ether have been obtained from oxidative cleavage of bicyclic precursors by treatment with acidic hydrogen peroxide in a process wh
Synthesis of curcuphenol methyl ether and 8-methoxycalamenene
Sattar, Abdus,Desai, Uday V .,Mane, Ramachandra B
, p. 446 - 448 (2007/10/02)
Friedel-Craft's acylation of m-cresol with glutaric anhydride, followed by esterification gives methyl 5-(2-hydroxy-4-methylphenyl)-5-oxopentanoate (4).Methylation of 4 followed by inverse Grignard reaction with methylmagnesium iodide yields an unsaturate
