66879-51-4Relevant academic research and scientific papers
Total Synthesis of (-)-Bacchopetiolone via an Asymmetric Hydroxylative Phenol Dearomatization/[4+2]-Dimerization Cascade Promoted by a Novel Salen-Type Chiral Iodane
Coffinier, Romain,Assal, Mourad El,Peixoto, Philippe A.,Bosset, Cyril,Miqueu, Karinne,Sotiropoulos, Jean-Marc,Pouységu, Laurent,Quideau, Stéphane
, p. 1120 - 1123 (2016/03/15)
The first total and biomimetic synthesis of the natural bis(sesquiterpene) (-)-bacchopetiolone (revised structure) was completed through a highly diastereoselective hydroxylative phenol dearomatization/[4+2]-dimerization cascade conversion of (+)-curcuphe
Syntheses of (±)-curcuphenol, (±)-curcudiol and (±)-curcuhydroquinone: A Johnson-Claisen rearrangement approach
Du, Zhen-Ting,Yu, Hong-Rui,Xu, Yan,Song, Qi-Liang,Li, An-Pai
, p. 399 - 403 (2011/04/22)
The synthesis of (±)-curcuphenol 1, (±)-curcudiol 2, (±)-curcuhydroquinone 3 and (±)-curcuquinone 4 had been achieved, in which the Johnson-Claisen rearrangement was used as key step.
Synthesis of bisabolane sesquiterpenes: A Johnson-Claisen rearrangement approach
Du, Zhen Ting,Yu, Hong Rui,Xu, Yan,Li, Yong,Li, An Pai
, p. 813 - 815 (2011/11/12)
Several bisabolane sesquiterpenes, (±)-curcumene, (±)-curcuphenol, (±)-curcudiol and (±)-curcuhydroquinone, have been synthesized in racemic form and fully characterized. The salient characteristic of our approach is that a Johnson-Claisen arrangement was
Facile syntheses of (±)-curcuphenol-(±)-curcudiol-±)- curcuhydroquinone, and (±)-curcuquinone
Du, Zhenting,Li, Yong,Wang, Yin,Ding, Lichun,Gao, Jinming
experimental part, p. 1920 - 1926 (2010/09/09)
The syntheses of (±)-curcuphenol 1, (±)-curcudiol 2, (±)-curcuhydroquinone 3, and (±)-curcuquinone 4 have been achieved. The key steps involved in the syntheses were the Reformatsky reaction and hydrogenation reaction. Copyright
Efficient total synthesis of racemic bisabolane sesquiterpenes curcuphenol and xanthorrhizol starting from substituted acetophenones
Montiel, Luisa E.,Zepeda, L. Gerardo,Tamariz, Joaquin
experimental part, p. 1261 - 1273 (2010/09/07)
A total synthesis of natural bisabolane sesquiterpenes curcuphenol (1) and xanthorrhizol (2) was developed by using the substituted acetophenones 4 and 5, respectively, as starting materials. The acetyl group of the latter was activated through ethoxycarb
Facile synthesis of (±)-parahigginone methyl ether and (±)-curcuphenol
Du, Zhen-Ting,Li, An-Pai,Peng, Kun,Wu, Tong-Xing,Pan, Xin-Fu
, p. 571 - 574 (2007/10/03)
Using Grinard coupling as a key step, a facile synthetic approach to (±)-parahigginone methyl ether 1 and (±)-curcuphenol 2 has been achieved by five steps with 42.3% and 58.6% overall yield, respectively.
Synthesis of (±) curcuphenol and (±)-β-sesquiphellandrene
Sharma,Chand, Tek
, p. 553 - 556 (2007/10/03)
Two naturally occurring compounds curcuphenol 1 and β-sesquiphellandrene 2 have been synthesised using lithium tetrachlorocuperate catalysed coupling reaction.
Synthesis of phenolic sesquiterpenes via oxidative cleavage of benzocycloalkenols
Ho, Tse-Lok,Yang, Po-Fei
, p. 181 - 192 (2007/10/02)
Phenolic sesquiterpenes including sesquichamaenol, 6-(2-hydroxy-4-methylphenyl)-2-methyl-3-heptanone, and curcuphenol methyl ether have been obtained from oxidative cleavage of bicyclic precursors by treatment with acidic hydrogen peroxide in a process wh
Synthesis of curcuphenol methyl ether and 8-methoxycalamenene
Sattar, Abdus,Desai, Uday V .,Mane, Ramachandra B
, p. 446 - 448 (2007/10/02)
Friedel-Craft's acylation of m-cresol with glutaric anhydride, followed by esterification gives methyl 5-(2-hydroxy-4-methylphenyl)-5-oxopentanoate (4).Methylation of 4 followed by inverse Grignard reaction with methylmagnesium iodide yields an unsaturate
