77516-58-6

Upstream product

• 5987-36-0 methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-α-D-altropyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 2280-44-6 D-Glucose 
• 6698-32-4 methyl 4,6-O-benzylidene-2-O-toluene-p-sulfonyl-α-D-glucopyranoside 
• 3162-96-7 methyl 4,6-O-benzylidene-α-D-glucopyranoside 
• 3150-16-1 methyl 4,6-O-benzylidene-2,3-anhydro-α-D-mannopyranoside 
• 20702-73-2 methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-α-D-ribo-hexopyranosid-2-ulose 
• 676-58-4 methylmagnesium chloride 

Downstream Products

• 77516-63-3 methyl 4-O-benzoyl-3,6-dideoxy-3-C-methyl-2-O-methyl-α-D-galactopyranoside 
• 77516-59-7 methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-2-O-methyl-α-D-glucopyranoside 
• 77516-64-4 1-O-acetyl-4-O-benzoyl-3,6-dideoxy-3-C-methyl-2-O-methyl-D-galactopyranose 
• 128037-90-1 [(3aS,5S,6R,7R,7aS)-6-(4-Methoxy-benzyloxy)-7-methyl-2-oxo-hexahydro-furo[3,2-b]pyran-5-yl]-acetic acid tert-butyl ester 
• 1027523-82-5 Acetic acid (2S,3R,4S,5R,6S)-5-benzyloxy-2-(chloro-phenylsulfanyl-methyl)-6-methoxy-4-methyl-tetrahydro-pyran-3-yl ester 
• 152838-07-8 methyl 4-O-acetyl-2-O-benzyl-3-deoxy-3-C-methyl-6-S-phenyl-6-thio-α-D-galactopyranoside 
• 85315-29-3 methyl 2-O-benzyl-4,6-O-benzylidene-3-deoxy-3-C-methyl-α-D-glucopyranoside 
• 152838-06-7 methyl 2-O-benzyl-3-deoxy-3-C-methyl-6-S-phenyl-6-thio-α-D-glucopyranoside 
• 85315-30-6 methyl 2-O-benzyl-3-deoxy-3-C-methyl-α-D-glucopyranoside 
• 73683-73-5 methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-α-D-glucopyranoside 

Relevant academic research and scientific papers

Assignment of the absolute configuration of blasticidin A and revision of that of aflastatin A

The absolute configuration of blasticidin A, a strong inhibitor of aflatoxin production by Aspergillus parasiticus, was assigned by adding the data of relative configurations at its diol and pentaol moieties to previously known stereochemistry. Similarity

A Carbohydrate Approach to Polyol Fragments of Amphotericin and the Trienomycin- and Mycotrienin Antibiotics

Hydrolytically labile ω-chloro-ω-phenylthioglycosides, obtained from the corresponding ω-phenylthioglycosides on treatment with NCS in CCl4, are readily dealkoxyhalogenated with Zn/Ag-graphite in anhydrous solvents affording enantiomerically pure synthons

TOTAL SYNTHESIS OF HALICHONDRINS: HIGHLY STEREOSELECTIVE CONSTRUCTION OF A HOMOCHIRAL PENTASUBSTITUTED H-RING PYRAN INTERMEDIATE FROM α-D-GLUCOSE

The functionality of α-D-Glucose is stereoselectively manipulated exploiting pyranose furanose pyranose interconversions and lactonization for selective masking to achieve a stereocontrolled synthesis of the densely substituted H-ring pyran of halichondrins.