67019-56-1

Basic information

• Product Name: 4'-methoxy-3,4,5,6-tetrahydro-[1,1'-biphenyl]-3-ol
• Synonyms: 4'-methoxy-3,4,5,6-tetrahydro-[1,1'-biphenyl]-3-ol
• CAS NO: 67019-56-1
• Molecular Weight: 204.269
• Mol File: 67019-56-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4'-methoxy-3,4,5,6-tetrahydro-[1,1'-biphenyl]-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-methoxy-3,4,5,6-tetrahydro-[1,1'-biphenyl]-3-ol(67019-56-1)
• EPA Substance Registry System: 4'-methoxy-3,4,5,6-tetrahydro-[1,1'-biphenyl]-3-ol(67019-56-1)

Safety Data

• Hazardous Substances Data: 67019-56-1(Hazardous Substances Data)

Upstream product

• 17159-98-7 3-(4-methoxyphenyl)-2-cyclohexen-1-one 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 930-68-7 cyclohexenone 
• 1206544-10-6 4′-methoxy-3,4-dihydro-[1,1′-biphenyl]-1(2H)-ol 
• 16807-60-6 3-methoxycyclohex-2-en-1-one 
• 504-02-9 1,3-cylohexanedione 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 117360-96-0 3-<(1-methylpropyl)oxy>-2-cyclohexen-1-one 

Downstream Products

• 67019-53-8 1-(2-(dimethylamino)ethyl)-4′-methoxy-1,2,3,4-tetrahydro-[1,1′-biphenyl]-4-ol 
• 34603-53-7 1-[2-(dimethylamino)ethyl]-4'-hydroxy-2,3-dihydro-[1,1'-biphenyl]-4(1H)-one 
• 17159-98-7 3-(4-methoxyphenyl)-2-cyclohexen-1-one 
• 1497432-32-2 3-(4-methoxyphenyl)cyclohex-2-enyl acetate 
• 1497432-43-5 C₂₆H₃₀O₃ 
• 1497432-49-1 (R)-4'-methoxy-3,4,5,6-tetrahydro-[1,1'-biphenyl]-3-ol 
• 1497432-44-6 (R)-3-(4-methoxyphenyl)cyclohex-2-enyl acetate 
• 34603-52-6 1-[2-(dimethylamino)ethyl]-4'-methoxy-2,3-dihydro-[1,1′-biphenyl]-4(1H)-one 
• 67019-52-7 2-(4′-methoxy-4-oxo-1,2,3,4-tetrahydro-[1,1′-biphenyl]-1-yl)-N,N-dimethylacetamide 
• 67019-55-0 2-(4'-methoxy-1,2,3,4-tetrahydro-[1,1'-biphenyl]-1-yl)-N,N-dimethylacetamide 
• 135068-48-3 4′,5-dimethoxy-2,3,4,5-tetrahydro-1,1′-biphenyl 

Relevant articles and documents

Arene Trifunctionalization with Highly Fused Ring Systems through a Domino Aryne Nucleophilic and Diels–Alder Cascade

A convenient and efficient domino aryne process was developed under transition-metal-free conditions to generate a range of tetra- and pentacyclic ring systems. This transformation was realized via a 1,2-benzdiyne through a nucleophilic and Diels–Alder reaction cascade using styrene as the diene moiety. Three new chemical bonds, namely one C?N and two C?C bonds, and two benzofused rings could be constructed concomitantly, which was made possible by distinct chemoselective control at both the 1,2-aryne and 2,3-aryne stages. Moreover, in-depth studies were carried out on the domino aryne precursors and controlling the diastereoselectivity.

Palladium-catalyzed oxidative rearrangement of tertiary allylic alcohols to enones with oxygen in aqueous solvent

A one-pot procedure for Pd(TFA)2-catalyzed 1,3-isomerization of tertiary allylic alcohols to secondary allylic alcohols followed by a Pd(TFA)2/neocuproine-catalyzed oxidative reaction to β-disubstituted-α,β-unsaturated kenones was developed. (Chemical Equation Presented).