67213-45-0

Basic information

• Product Name: 2-phenylethanol-1,2-d₂
• Synonyms: 2-phenylethanol-1,2-d₂
• CAS NO: 67213-45-0
• Molecular Weight: 124.151
• Mol File: 67213-45-0.mol

Chemical Properties

• CAS DataBase Reference: 2-phenylethanol-1,2-d₂(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenylethanol-1,2-d₂(67213-45-0)
• EPA Substance Registry System: 2-phenylethanol-1,2-d₂(67213-45-0)

Safety Data

• Hazardous Substances Data: 67213-45-0(Hazardous Substances Data)

Upstream product

• 22139-13-5 (E,Z)-[β-D₁]styrene 
• 103-64-0 bromostyrene 
• 100-42-5 styrene 
• 66255-92-3 (R)-(+)-styrene-2,2-d2 oxide 

Downstream Products

• 26631-76-5 2-phenylethyl-1,2-d₂ tosylate 
• 21148-24-3 (+/-)-threo-1-chloro-2-phenyl-1,2-d2 ethane 
• 26631-77-6 2-phenylethyl-1,2-d₂-dimethylamine 
• 104960-11-4 2-(p-nitrophenyl)ethyl-1,2-d₂-dimethylamine 
• 104960-08-9 2-phenylethyl-1,2-d₂-trimethylammonium iodide 
• 104960-12-5 2-(p-nitrophenyl)ethyl-1,2-d₂-trimethylammonium iodide 

Relevant articles and documents

CATALYTIC ANTI-MARKOVNIKOV OXIDATION AND HYDRATION OF OLEFINS

The disclosure provides a dual-catalysis system for direct conversion of olefins to alcohols. The cooperative catalytic system contains one oxidizing catalyst and one transfer-hydrogenation catalyst. A wide variety of olefins, including aromatic and aliphatic olefins, can be used as the reactant. The transformation proceeds with anti-Markovnikov selectivity, and in some aspects provides primary alcohols as major products. The disclosure further provides a system for oxidation of olefins with anti-Markovnikov selectivity.

Mechanism of elimination rections. 40. Attempted study of stereochemistry of elimination from 2-(p-nitrophenyl)ethyltrimmethylammonium ion. Base-promoted cis-trans isomerization of p-nitrostyrene-β-d1

Stereospecifically deuterated ArCHDCHDNMe3+I- and ArCHDCHDNMe2O have been prepared, where Ar=C6H5 and p-NO2C6H4.When Ar=C6H5, the elimination reaction of the quaternery salt with ethoxide in ethanol goes with >98percent anti stereoch

Stereochemical Course of the "Mixed Hydride" (AlD3 and AlCl2H) Reduction of Optically Active Styrene-2,2-d2 Oxide

The reduction of (R)-(+)-styrene-2,2-d2 oxide with aluminum deuteride (AlD3) in diethyl ether at 0 deg C gives a nearly equal mixture of (S)-(+)-1-phenylethanol-2,2,2-d3 and (S)-(-)-2-phenylethanol-1,1,2-d3, the latter being formed with almost complete in