67213-45-0Relevant articles and documents
CATALYTIC ANTI-MARKOVNIKOV OXIDATION AND HYDRATION OF OLEFINS
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Page/Page column 18, (2012/07/14)
The disclosure provides a dual-catalysis system for direct conversion of olefins to alcohols. The cooperative catalytic system contains one oxidizing catalyst and one transfer-hydrogenation catalyst. A wide variety of olefins, including aromatic and aliphatic olefins, can be used as the reactant. The transformation proceeds with anti-Markovnikov selectivity, and in some aspects provides primary alcohols as major products. The disclosure further provides a system for oxidation of olefins with anti-Markovnikov selectivity.
Mechanism of elimination rections. 40. Attempted study of stereochemistry of elimination from 2-(p-nitrophenyl)ethyltrimmethylammonium ion. Base-promoted cis-trans isomerization of p-nitrostyrene-β-d1
Dohner, Brent R.,Saunders, William H., Jr.
, p. 1026 - 1030 (2007/10/02)
Stereospecifically deuterated ArCHDCHDNMe3+I- and ArCHDCHDNMe2O have been prepared, where Ar=C6H5 and p-NO2C6H4.When Ar=C6H5, the elimination reaction of the quaternery salt with ethoxide in ethanol goes with >98percent anti stereoch
Stereochemical Course of the "Mixed Hydride" (AlD3 and AlCl2H) Reduction of Optically Active Styrene-2,2-d2 Oxide
Elsenbaumer, R. L.,Mosher, Harry S.,Morrison, James D.,Tomaszewski, J. E.
, p. 4034 - 4038 (2007/10/02)
The reduction of (R)-(+)-styrene-2,2-d2 oxide with aluminum deuteride (AlD3) in diethyl ether at 0 deg C gives a nearly equal mixture of (S)-(+)-1-phenylethanol-2,2,2-d3 and (S)-(-)-2-phenylethanol-1,1,2-d3, the latter being formed with almost complete in