6737-43-5

Upstream product

• 629-27-6 1-Iodooctane 
• 829-85-6 diphenylphosphane 
• 111-83-1 1-bromo-octane 
• 603-35-0 triphenylphosphine 
• 124-13-0 Octanal 
• 1079-66-9 chloro-diphenylphosphine 
• 111-66-0 oct-1-ene 
• 150529-78-5 1-octylzinc(II) iodide 
• 14403-26-0 dioctylzinc 
• 15475-27-1 potassium diphenylphosphine 

Downstream Products

• 176445-51-5 2-{2-[2-(Octyl-phenyl-phosphanyl)-ethoxy]-ethoxy}-ethanol 
• 29701-85-7 diphenyl-n-oct-1-ylphosphine oxide 

Relevant academic research and scientific papers

Ln(ii) amido complexes coordinated by ring-expanded N-heterocyclic carbenes-promising catalysts for olefin hydrophosphination

First Ln(ii) ring-expanded NHC complexes (er-NHC)Ln[N(SiMe3)2]2 (Ln = Sm, Yb) are synthesized and proved to be highly efficient pre-catalysts for the intermolecular hydrophosphination of such indolent substrates as 1-alkenes, cyclohexene and norbornene. This journal is

Versatile Visible-Light-Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts

Asymmetrically substituted tertiary phosphines and quaternary phosphonium salts are used extensively in applications throughout industry and academia. Despite their significance, classical methods to synthesize such compounds often demand either harsh reaction conditions, prefunctionalization of starting materials, highly sensitive organometallic reagents, or expensive transition-metal catalysts. Mild, practical methods thus remain elusive, despite being of great current interest. Herein, we describe a visible-light-driven method to form these products from secondary and primary phosphines. Using an inexpensive organic photocatalyst and blue-light irradiation, arylphosphines can be both alkylated and arylated using commercially available organohalides. In addition, the same organocatalyst can be used to transform white phosphorus (P4) directly into symmetrical aryl phosphines and phosphonium salts in a single reaction step, which has previously only been possible using precious metal catalysis.

STABILIZATION OF ACTIVE METAL CATALYSTS AT METAL-ORGANIC FRAMEWORK NODES FOR HIGHLY EFFICIENT ORGANIC TRANSFORMATIONS

Metal-organic framework (MOFs) compositions based on post?synthetic metalation of secondary building unit (SBU) terminal or bridging OH or OH2 groups with metal precursors or other post-synthetic manipulations are described. The MOFs provide a versatile family of recyclable and reusable single-site solid catalysts for catalyzing a variety of asymmetric organic transformations, including the regioselective boryiation and siiylation of benzyiic C—H bonds, the hydrogenation of aikenes, imines, carbonyls, nitroarenes, and heterocycles, hydroboration, hydrophosphination, and cyclization reactions. The solid catalysts can also be integrated into a flow reactor or a supercritical fluid reactor.

Alkyl diphenyl phosphine and preparing alkyl diphenyl phosphine payment proportional to production alkyl benzene

The invention discloses alkyl diphenylphosphine and a method for preparing alkyl diphenylphosphine with co-production of alkylbenzene. The structural formula of alkyl diphenylphosphine is shown in a formula I. The method comprises: adding triphenylphosphine and metal lithium into an organic solvent for reaction for 3-6 hours at room temperature; and cooling the reaction system to 0-10 DEG C, adding halogenated straight-chain alkane for insulating reaction, then raising the temperature of the system to 30-80 DEG C, keeping the temperature to react for 1-3 hours, removing the organic solvent and reducing the pressure and distilling to separately obtain alkyl diphenylphosphine and alkylbenzene. According to the alkyl diphenylphosphine disclosed by the invention, alkyl is directly bonded with P, so that the alkyl diphenylphosphine can be dissolved in most solvents and can be used as a ligand for homogeneous catalysts. By virtue of the method disclosed by the invention, high value straight-chain alkylbenzene is co-produced while straight-chain alkyl diphenylphosphine is prepared by way of a one-pot process. Use of chloro-tert-butane which is relatively high in price and waste of the metal lithium are avoided. The method is simple to operate, efficient, low in energy consumption, low in cost and suitable for large-scaled industrial production.

With machine phosphine molybdenum complex, preparation method and application

The invention discloses an organic phosphonium molybdenum complex, a preparation method and application. The organic phosphonium molybdenum complex has the following general formula: Mo[P(Ph)2R]2Cl5, wherein the P(Ph)2R is alkyldiphenylphosphine; the R is linear-chain alkyl with the carbon atom number of 3-10. According to the organic phosphonium molybdenum complex provided by the invention, alkyldiphenylphosphine is adopted as the ligand, and the organic phosphonium molybdenum complex can be dissolved in dicyclopentadiene, and can form a homogeneous system with dicyclopentadiene when used as a main catalyst to catalyze dicyclopentadiene for ring opening polymerization, so that the catalytic efficiency is greatly improved, and the production efficiency of polydicyclopentadiene is improved; the organic phosphonium molybdenum complex is relatively high in catalytic activity, and the polydicyclopentadiene product prepared through adopting the organic phosphonium molybdenum complex as the main catalyst is high in quality and excellent in the mechanical properties, such as, tensile strength and impact strength; the organic phosphonium molybdenum complex is relatively high in chemical stability, insensitive to air and moisture, simple in preparation, low in cost and suitable for popularization and application.

Cerium-Hydride Secondary Building Units in a Porous Metal-Organic Framework for Catalytic Hydroboration and Hydrophosphination

We report the stepwise, quantitative transformation of CeIV6(μ3-O)4(μ3-OH)4(OH)6(OH2)6 nodes in a new Ce-BTC (BTC = trimesic acid) metal-organic framework (

Ph2PI as a reduction/phosphination reagent: Providing easy access to phosphine oxides

The reaction of aldehydes with Ph2PI provides a facile way to the synthesis of pentavalent phosphine compounds with moderate to good yields.

Copper(I)-catalyzed hydrophosphination of styrenes

Hydrophosphination of styrenes has been accomplished with metal salts for the first time. (CuOTf)2·toluene complex is the catalyst of choice, but CuCl can also be used. "In-situ" EPR and NMR studies suggest Cu(I) as the catalytically active metal species, giving exclusively the anti-Markovnikov product. Phosphine oxides or β-ketophosphine oxides can be prepared in one-pot by oxidation with molecular oxygen.

Monophosphine and diphosphine ligands for diplatinum polyynediyl complexes: Efficient syntheses of new functionality-containing systems and model compounds

Br(CH2)4Br and NaO(CH2)2CH{double bond, long}CH2 react under suitable conditions to give Br(CH2)4O(CH2)2CH{double bond, long}CH2 (55%), which is

Preparation of polyfunctional phosphines using zinc organometallics

The reaction of functionalized diorganozincs with chlorodiorganophosphines provides polyfunctional phosphines in good yields. Especially attractive is the hydroboration/boron-zinc exchange sequence which allows the conversion of functionalized olefins into polyfunctional phosphines in a one-pot procedure. Several new chiral phosphines have been prepared starting from readily available chiral olefins (terpenes) and their efficiency in asymmetric hydrogenation reactions has been evaluated.