67464-46-4

Basic information

• Product Name: phenanthrene 9,10-imine
• Synonyms: phenanthrene 9,10-imine
• CAS NO: 67464-46-4
• Molecular Formula: C₁₄H₁₁N
• Molecular Weight: 193.2438
• Mol File: 67464-46-4.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 343.5°Cat760mmHg
• Flash Point: 175.4°C
• Appearance: /
• Density: 1.201g/cm³
• Vapor Pressure: 7E-05mmHg at 25°C
• Refractive Index: 1.665
• CAS DataBase Reference: phenanthrene 9,10-imine(CAS DataBase Reference)
• NIST Chemistry Reference: phenanthrene 9,10-imine(67464-46-4)
• EPA Substance Registry System: phenanthrene 9,10-imine(67464-46-4)

Safety Data

• Hazardous Substances Data: 67464-46-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H11N/c1-3-7-11-9(5-1)10-6-2-4-8-12(10)14-13(11)15-14/h1-8,13-15H

Upstream product

• 1210-05-5 Biphenyl-2,2'-dicarbaldehyde 
• 106569-00-0 2'-Aminomethyl-biphenyl-2-carbaldehyde 
• 53581-32-1 (+/-)-trans-9-Azido-10-hydroxy-9,10-dihydrophenanthrene 
• 316-31-4 5H-dibenzazepine 
• 106568-96-1 2-(2'-formyl-<1,1'-biphenyl>-2-yl)-1,3-dioxolane oxime 
• 13404-97-2 2'-(bromomethyl)<1,1'-biphenyl>-2-carboxaldehyde 

Downstream Products

• 99941-32-9 1--1a,9b-dihydrophenanthro<9,10-b>azirine 
• 91540-30-6 N-(2-propenyl)phenanthrene 9,10-imine 
• 81593-12-6 trans-9,10-dihydro-9-(4-methyl)benzenesulfonamido-10-(phenylmethyl)thiophenanthrene 
• 60883-97-8 1a,9b-dihydro-1-<(4-methylphenyl)sulfonyl>-1H-phenanthro<9,10-b>azirine 
• 4235-09-0 9-(N-acetylamino)phenanthrene 
• 81593-13-7 diethyl 1a,9b-dihydro-1-phosphonato-1H-phenanthro<9,10-b>azirine 
• 81593-08-0 N-9-phenanthrenylbenzamide 
• 81593-15-9 1-chloro-1a,9b-dihydro-1H-<9,10-b>azirine 
• 947-73-9 9-Aminophenanthrene 
• 16269-40-2 N-9-phenanthrenyl-9-phenanthrenamine 
• 215-14-5 phenanthrazine 
• 88090-59-9 9H-tetrabenzocarbazole 
• 85-01-8 phenanthrene 

Relevant articles and documents

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The Chemistry of Polycyclic Arene Imine. VI. 1--1a,9b-dihydrophenanthroazirine an Unusual Allylation Product of Phenanthrene 9,10-Imine

Phenanthrene 9,10-imine (1) was shown to react with allyl bromide and 50percent aqueous sodium hydroxide under phase transfer catalysis conditions to give the title compound 3 as the only product.The starting imine 1 is assumed to undergo initially bis alkylation to form an N,N-di-(2-propenyl)phenanthrene 9,10-iminium salt (4) which, in turn, is attacked by a deprotonated phenanthrene imine anion (5).The structure of 3 has been determined by a single crystal X-ray diffraction analysis.