67464-46-4

Usage

InChI:InChI=1/C14H11N/c1-3-7-11-9(5-1)10-6-2-4-8-12(10)14-13(11)15-14/h1-8,13-15H

Upstream product

• 316-31-4 5H-dibenzazepine 
• 1210-05-5 Biphenyl-2,2'-dicarbaldehyde 
• 13404-97-2 2'-(bromomethyl)<1,1'-biphenyl>-2-carboxaldehyde 
• 53581-32-1 (+/-)-trans-9-Azido-10-hydroxy-9,10-dihydrophenanthrene 
• 106568-96-1 2-(2'-formyl-<1,1'-biphenyl>-2-yl)-1,3-dioxolane oxime 
• 106569-00-0 2'-Aminomethyl-biphenyl-2-carbaldehyde 

Downstream Products

• 16269-40-2 N-9-phenanthrenyl-9-phenanthrenamine 
• 88090-59-9 9H-tetrabenzocarbazole 
• 85-01-8 phenanthrene 
• 947-73-9 9-Aminophenanthrene 
• 215-14-5 phenanthrazine 
• 81593-15-9 1-chloro-1a,9b-dihydro-1H-<9,10-b>azirine 
• 81593-08-0 N-9-phenanthrenylbenzamide 
• 4235-09-0 9-(N-acetylamino)phenanthrene 
• 99941-32-9 1--1a,9b-dihydrophenanthro<9,10-b>azirine 
• 91540-30-6 N-(2-propenyl)phenanthrene 9,10-imine 
• 81593-12-6 trans-9,10-dihydro-9-(4-methyl)benzenesulfonamido-10-(phenylmethyl)thiophenanthrene 
• 60883-97-8 1a,9b-dihydro-1-<(4-methylphenyl)sulfonyl>-1H-phenanthro<9,10-b>azirine 
• 81593-13-7 diethyl 1a,9b-dihydro-1-phosphonato-1H-phenanthro<9,10-b>azirine 

Relevant academic research and scientific papers

Syntheses and Chemistry of Some Dibenzazepines

5-Methyl-, 5,7-dimethyl-, and 5,7-diphenyl-substituted and unsubstituted 5H-dibenzazepines were prepared by two general routes from -2,2'-dicarboxaldehyde.The unsubstituted dibenzazepine was converted into 1a,9b-dihydrophenanthro9,10-

The Chemistry of Polycyclic Arene Imine. VI. 1--1a,9b-dihydrophenanthroazirine an Unusual Allylation Product of Phenanthrene 9,10-Imine

Phenanthrene 9,10-imine (1) was shown to react with allyl bromide and 50percent aqueous sodium hydroxide under phase transfer catalysis conditions to give the title compound 3 as the only product.The starting imine 1 is assumed to undergo initially bis alkylation to form an N,N-di-(2-propenyl)phenanthrene 9,10-iminium salt (4) which, in turn, is attacked by a deprotonated phenanthrene imine anion (5).The structure of 3 has been determined by a single crystal X-ray diffraction analysis.

The Chemistry of Polycyclic Arene Imines. II. Photochemistry of Phenanthrene 9,10-Imine and of Its N-Butyl Derivative

The uv irradiation of phenanthrene-9,10-imine has been shown to give 9H-tetrabenzocarbazole as the major photo-product both in argon purged acetone and in dichloromethane.Phenanthrazine, N-9-phenanthrenyl-9-phenanthrenamine and phenanthrene were formed in smaller quantities. 9-Phenanthrenamine was found to be a minor by-product.N-Butylphenanthrene 9,10-imine yielded under similar conditions phenanthrene and N-butyl-9-phenanthrenamine as the only isolable polycyclic compounds.In the presence of air the substituted imine gave mainly 2-propylphenanthrooxazole.