676-89-1

Basic information

• Product Name: trimethyltin tetrafluoroborate
• CAS NO: 676-89-1
• Molecular Weight: 250.619
• Mol File: 676-89-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trimethyltin tetrafluoroborate(CAS DataBase Reference)
• NIST Chemistry Reference: trimethyltin tetrafluoroborate(676-89-1)
• EPA Substance Registry System: trimethyltin tetrafluoroborate(676-89-1)

Safety Data

• Hazardous Substances Data: 676-89-1(Hazardous Substances Data)

Upstream product

• 14064-15-4 (4-chlorophenyl)trimethylstannane 
• 17113-81-4 trimethyl(3-(trifluoromethyl)phenyl)stannane 
• 14064-16-5 <4-(Dimethylamino)phenyl>trimethylstannan 
• 17113-79-0 trimethyl(4-(methylthio)phenyl)stannane 
• 17315-44-5 (3-fluoro-phenyl)-trimethyl-stannane 
• 14101-14-5 (4-fluorophenyl)trimethyltin 
• 937-11-1 (4-bromophenyl)trimethylstannane 
• 937-12-2 4-tolyltrimethylstannane 
• 934-56-5 trimethyl(phenyl)stannane 
• 940-00-1 (4-methoxyphenyl)trimethylstannane 
• 7637-07-2 boron trifluoride 
• 1015-53-8 (pentafluorophenyl)trimethyltin 
• 594-27-4 tetramethylstannane 

Relevant articles and documents

Mechanism of Addition of Aryltrimethyl-silanes and -stannanes to Tricarbonyl(cyclohexadienyl)ruthenium(II) Cation

Kinetic studies of the reaction between the organometallic complex BF4 (1) and aryltrimethyl-silanes and -stannanes of the type XC6H4M'Me3 (M' = Si or Sn; X = H, 4-NMe2, 4-OMe, 1-OMe, 4-Me, 4-SMe, 4-F, 4-Cl, 4-Br, 3-F, or 3-CF3) reveal the rate law, rate = k.This rate law has been rationalised in terms of a rate-determining electrophilic attack by complex (1) on the XC6H4M'Me3 substrates to form Wheland type ?-complex intermediates of the type (2) followed by cleavage of the Me3M-C(dienyl) bond to give the new compunds (3).These reactions are of considerable synthetic interest as they offer useful routes to otherwise inaccessible substituted benzenoid derivatives.For the Sn reactions, a Hammett plot of log (kX/kH) versus ? (the standard Hammett substituent constant) is linear with a slope of -2.9 suggesting a common mechanism for each of the reactions.A plot of log (kX/kH) for the reactions of (1) with XC6H4SnMe3 in MeNO2 (at 45 deg C) versus log(kX/kH) for the protiodemetallation of XC6H4Sn(cyclo-C6H11)3 by HClO4 in aqueous ethanol (at 50 deg C) is also linear indicating that organometallic complexes such as (1) behave in a similar manner to more classical electrophiles.