937-11-1

Upstream product

• 1066-45-1 trimethyltin(IV)chloride 
• 22480-64-4 4-bromophenyllithium 
• 661-69-8 hexamethyldistannane 
• 106-40-1 4-bromo-aniline 
• 56075-37-7 1-(methylsulfonyl)-2-(4-bromophenyl)diazene 
• 1066-44-0 trimethyltin bromide 
• 18620-02-5 (4-bromophenyl)magnesium bromide 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 103185-00-8 1-bromo-4-[¹⁸F]fluorobenzene 
• 1012-73-3 1,4-bis(trimethylstannyl)benzene 
• 5359-55-7 ethyl 2-(4-bromophenyl)-2-phenylacetate 
• 1365610-77-0 (CH₃)3SnC₆H₄(CH₂)3CO₂C₂H₅ 
• 29544-49-8 (CH₃)3SnC₆H₄-p-Si(CH₃){Si(CH₃)3}2 
• 29488-92-4 (CH₃)3SnC₆H₄-p-Si(CH₃)2Si(CH₃)3 
• 147427-18-7 phenyl(4-(trimethylstannyl)phenyl)methanone 
• 1066-44-0 trimethyltin bromide 
• 125928-70-3 4-trimethylstannylbenzoic acid 
• 1066-45-1 trimethyltin(IV)chloride 
• 944-32-1 1-trimethylsilyl-(4-trimethylstannyl)benzene 
• 676-89-1 trimethyltin tetrafluoroborate 

Relevant academic research and scientific papers

Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones

The visible-light-driven preparation of (hetero)aryl stannanes was carried out under both photocatalyst- and metal-free conditions via irradiation of arylazo sulfones in the presence of hexaalkyldistannanes. The reaction shows a high efficiency and a wide substrates scope. The resulting crude organotin derivatives can be directly employed in a Stille protocol.

Synthesis of aryl trimethylstannanes from aryl amines: A sandmeyer-type stannylation reaction

Sandmeyer-type stannylation: Stille coupling is one of the most powerful coupling reactions for C-C bond formation, whereas there are only limited methods to access aryl stannane compounds. A mild stannylation process based on a Sandmeyer-type transformation using aromatic amines as the starting materials is described. DCE: 1,2-dichloroethane. Copyright

Organosilicon compounds. XLVII. The substituent effects and leaving group abilities of mono-, bis- and tris-(trimethylsilyl)silyl groups in electrophilic aromatic substitution

The rates of cleavage at 50° by a mixture of ethanol (5 vol) and aqueous perchloric acid (2 vol) of the aryl-SnMe3 bonds of p-[(Me3Si)xMe(3-x)Si]C6H4SnMe3 compounds relative to that of phenyltrimethylstannane have been found to be 0.93 (x = 0), 1.31 (x = 1), 1.67 (x = 2) and 1.76 (x = 3). The increase in rate with the increasing magnitude of x can be attributed to inductive and hyperconjugative electron release from the SiSi bonds. The rates of cleavage at 50° by a mixture of methanol (5 vol) and aqueous perchloric acid (2 vol) of the aryl-Si bonds of the compounds [(Me3Si)xMe(3-x)Si]Ph are 1.0 (x = 0), 2.1 (x = 1), 0.35 (x = 2), and 0.056 (x = 3). The reactivity sequence as x is increased is attributed to opposition between a rate enhancement associated with the increasing electron release and a rate retardation associated with increasing steric hindrance, especially hindrance to solvation of the transition state.