14101-14-5

Basic information

• Product Name: 4-Fluorophenyltrimethylstannane
• Synonyms: (4-Fluorophenyl)trimethylstannane;1-(Trimethylstannyl)-4-fluorobenzene;4-Fluorophenyltrimethylstannane;Trimethyl(4-fluorophenyl)stannane
• CAS NO: 14101-14-5
• Molecular Formula: C₉H₁₃FSn
• Molecular Weight: 0
• Mol File: 14101-14-5.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-Fluorophenyltrimethylstannane(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Fluorophenyltrimethylstannane(14101-14-5)
• EPA Substance Registry System: 4-Fluorophenyltrimethylstannane(14101-14-5)

Safety Data

• Hazardous Substances Data: 14101-14-5(Hazardous Substances Data)

Upstream product

• 661-69-8 hexamethyldistannane 
• 371-40-4 4-fluoroaniline 
• 352-33-0 1-Chloro-4-fluorobenzene 
• 1066-44-0 trimethyltin bromide 
• 352-13-6 4-flourophenylmagnesium bromide 
• 1066-45-1 trimethyltin(IV)chloride 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 352-34-1 4-fluoro-1-iodobenzene 

Downstream Products

• 312-31-2 4-(phenylsulfonyl)fluorobenzene 
• 149099-27-4 4-fluorobenzhydrol 
• 1247019-57-3 ethyl 1-cyclopropyl-6-fluoro-7-(4-fluorophenyl)-8-nitro-4-oxo-1,4-dihydroquinoline-3-carboxylate 
• 540-36-3 para-difluorobenzene 
• 1493-23-8 (4-fluorophenyl)lithium 
• 289656-89-9 (3-fluorophenyl)bis(4-fluorophenyl)methanol 
• 345-71-1 (3-fluorophenyl)(4-fluorophenyl)methanone 
• 1610606-35-3 (Cy₃P)Au(4-F-C₆H₄)(CF₃)(I) 
• 1307863-49-5 ethyl 7-cyclopropyl-2-(4-fluorophenyl)-3-nitro-4-oxo-4,7-dihydrothieno[2,3-b]pyridine-5-carboxylate 
• 1066-45-1 trimethyltin(IV)chloride 
• 676-89-1 trimethyltin tetrafluoroborate 
• 370557-68-9 α-Benzoyl(4-fluorophenyl)phenylmethanol 

Relevant articles and documents

Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones

The visible-light-driven preparation of (hetero)aryl stannanes was carried out under both photocatalyst- and metal-free conditions via irradiation of arylazo sulfones in the presence of hexaalkyldistannanes. The reaction shows a high efficiency and a wide substrates scope. The resulting crude organotin derivatives can be directly employed in a Stille protocol.

Synthesis of aryl trimethylstannanes from aryl halides: An efficient photochemical method

An efficient transition-metal-free photochemical method featuring excellent functional group tolerance, mild reaction conditions and short reaction times has been discovered and developed for the synthesis of (hetero)aryl trimethylstannanes from (hetero)aryl halides. A photo-initiated radical chain mechanism was proposed based on preliminary mechanistic studies.