14101-14-5

Upstream product

• 1066-45-1 trimethyltin(IV)chloride 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 661-69-8 hexamethyldistannane 
• 371-40-4 4-fluoroaniline 
• 352-33-0 1-Chloro-4-fluorobenzene 
• 352-34-1 4-fluoro-1-iodobenzene 
• 1066-44-0 trimethyltin bromide 
• 352-13-6 4-flourophenylmagnesium bromide 

Downstream Products

• 312-31-2 4-(phenylsulfonyl)fluorobenzene 
• 149099-27-4 4-fluorobenzhydrol 
• 370557-68-9 α-Benzoyl(4-fluorophenyl)phenylmethanol 
• 676-89-1 trimethyltin tetrafluoroborate 
• 1066-45-1 trimethyltin(IV)chloride 
• 1247019-57-3 ethyl 1-cyclopropyl-6-fluoro-7-(4-fluorophenyl)-8-nitro-4-oxo-1,4-dihydroquinoline-3-carboxylate 
• 1307863-49-5 ethyl 7-cyclopropyl-2-(4-fluorophenyl)-3-nitro-4-oxo-4,7-dihydrothieno[2,3-b]pyridine-5-carboxylate 
• 540-36-3 para-difluorobenzene 
• 1493-23-8 (4-fluorophenyl)lithium 
• 289656-89-9 (3-fluorophenyl)bis(4-fluorophenyl)methanol 
• 345-71-1 (3-fluorophenyl)(4-fluorophenyl)methanone 
• 1610606-35-3 (Cy₃P)Au(4-F-C₆H₄)(CF₃)(I) 

Relevant academic research and scientific papers

Reductive Electrophotocatalysis: Merging Electricity and Light to Achieve Extreme Reduction Potentials

We describe a new electrophotocatalytic strategy that harnesses the power of light and electricity to generate an excited radical anion with a reducing potential of -3.2 V vs SCE, which can be used to activate substrates with very high reduction potentials (Ered ≈ -1.9 to -2.9 V). The resultant aryl radicals can be engaged in various synthetically useful transformations to furnish arylboronate, arylstannane, and biaryl products.

Synthesis of Aryl Trimethylstannane via BF3·OEt2-Mediated Cross-Coupling of Hexaalkyl Distannane Reagent with Aryl Triazene at Room Temperature

BF3·OEt2-mediated cross-coupling of (SnMe3)2 with aryl triazene offers a new strategy for the synthesis of aryl stannane. A variety of synthetically useful aryl trimethylstannanes were produced in moderate to good yields with this metal-free approach. One-pot sequential Stille cross-coupling with different aryl bromides provides a short entry to both symmetrical and unsymmetrical biaryl compounds.

Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones

The visible-light-driven preparation of (hetero)aryl stannanes was carried out under both photocatalyst- and metal-free conditions via irradiation of arylazo sulfones in the presence of hexaalkyldistannanes. The reaction shows a high efficiency and a wide substrates scope. The resulting crude organotin derivatives can be directly employed in a Stille protocol.

Synthesis of aryl trimethylstannanes from aryl halides: An efficient photochemical method

An efficient transition-metal-free photochemical method featuring excellent functional group tolerance, mild reaction conditions and short reaction times has been discovered and developed for the synthesis of (hetero)aryl trimethylstannanes from (hetero)aryl halides. A photo-initiated radical chain mechanism was proposed based on preliminary mechanistic studies.

1,2-AZABORINE COMPOUNDS AND SYNTHESIS

A compound, or a pharmaceutically acceptable salt or ester thereof, having a structure of formula (I), wherein R1 is a substituted aryl or an optionally-substituted heteroaryl, provided that the heteroaryl is not pyridyl or azaborine; and each

Synthesis of aryl trimethylstannanes from aryl amines: A sandmeyer-type stannylation reaction

Sandmeyer-type stannylation: Stille coupling is one of the most powerful coupling reactions for C-C bond formation, whereas there are only limited methods to access aryl stannane compounds. A mild stannylation process based on a Sandmeyer-type transformation using aromatic amines as the starting materials is described. DCE: 1,2-dichloroethane. Copyright

Rhodium-catalyzed boron arylation of 1,2-azaborines

A Sn-phony in B! BN isosteres of biphenyl compounds are prepared through Rh-catalyzed cross-coupling between 2-chloro-1,2-azaborines and arylstannanes (see scheme). The synthetic method should enable investigations of structure-activity relationships (SAR

Azoxy compound

An azoxy compound represented by the following general formula STR1 wherein R1 denotes a hydrogen atom, a halogen atom, a hydroxyl group, a lower alkoxy group, a lower alkoxy-lower alkoxy group or a group of the formula X1 --C C--CH

SYNTHESIS AND SPECTROSCOPIC CHARACTERISTICS OF ARYLTRIMETHYL-SILICON, -GERMANIUM, AND -TIN COMPOUNDS

The synthesis and spectroscopic characteristics of 28 para-substituted aryltrimethyl-silicon, -germanium, and -tin compounds are described.The infrared spectra show characteristic bands at 1245-1165 (methyl bend), 840-765 (methyl rock), and 1105-1020 (in-plane aromatic H bend) cm-1; the frequency of the last band was found to depend on the sum of the aromatic substituent masses, the presence or absence of metallic constituents in the substituent having little influence.The mass spectral fragmentation patterns are interpreted in terms of localization of positive charge on the metal atom, with subsequent bond cleavage behavior which obeys the rules for mass spectra of carbon compounds.