14064-16-5

Upstream product

• 1066-45-1 trimethyltin(IV)chloride 
• 13190-50-6 4-dimethylaminophenyllithium 
• 1066-44-0 trimethyltin bromide 
• 586-77-6 4-bromo-N,N-dimethylaniline 
• 661-69-8 hexamethyldistannane 

Downstream Products

• 26772-93-0 N-(4-chlorophenyl)-N-methylformamide 
• 121-69-7 N,N-dimethyl-aniline 
• 57650-42-7 tricarbonyl[5-(4-dimethylaminophenyl)cyclohexa-1,3-diene]iron 
• 17197-38-5 {(CH₃)3SnC₆H₄-p-N(CH₃)3}I 
• 56-24-6 trimethyltin(IV) hydroxide 
• 676-89-1 trimethyltin tetrafluoroborate 
• 71743-94-7 Fe(CO)3(C₆H₆CH₃OC₆H₄N(CH₃)2) 

Relevant academic research and scientific papers

On the reaction of 4-substituted trimethyltin aromatics with perchlorylfluoride

To evaluate the suitability of [18F]perchorylfluoride [18F]FClO3 as an electrophilic fluorination agent for the preparation of radiopharmaceuticals, the reactivity non-radioactive FClO3 towards 4-substituted trimethyltin aromatic compounds was studied. Contrary to the expectation, an electrophilic fluorination of the aromatic nucleus did not occur. The reaction of perchlorylfluoride with aromatic trimethylstannyl compounds resulted in the formation of trimethyltin fluoride and the respective destannylated aromatics in variable yields.

SYNTHESIS OF ORGANOTRIALKYLSTANNANES. THE REACTION BETWEEN ORGANIC HALIDES AND HEXAALKYLDISTANNANES IN THE PRESENCE OF PALLADIUM COMPLEXES

The aryl halides YC6H4X (X=Br or I) have been shown to react with the distannanes (R3Sn)2 (R=n-Bu or Me) in toluene in the presence of or to give the compounds YC6H4SnR3 for (a) R=n-Bu, Y=H, p-OMe, o-Me, p-Me, m-Cl, p-Cl, m-CN, p-COCH3 and m-NO2, and (b) R=Me, Y=H, p-OMe, p-Me, p-CN, p-COCH3, m-NO2 and p-NO2.Benzyl halides YC6H4CH2X (X=Cl or Br) similarly give YC6H4CH2SnR3 for (a) R=n-Bu, Y=H, m-OMe, p-OMe, m-Cl, m-CN, and m-NO2, and (b) R=Me, Y=m-Cl, m-CN, p-CN and m-NO2.These reactions are of special value as preparative procedures in cases in which Grignard or organolithium reagents cannot be used.Allyl chloride and bromide were likewise shown to react with (n-Bu3Sn)2 to give CH2=CHCH2SnBu3, but n-BuCl and n-BuBr gave only a trace of n-Bu4Sn.The mixed dimetallo species n-Bu3SnSiMe3 was shown to react with aryl bromides YC6H4Br (X=H, p-OMe, p-Me, or p-Cl) to give the arylsilicon compounds YC6H4SiMe3, with no aryltin products.