67630-76-6Relevant academic research and scientific papers
Anion selectivity in zwitterionic amide-functionalised metal salt extractants
Galbraith, Stuart G.,Wang, Qiang,Li, Li,Blake, Alexanders,Wilson, Claire,Collinson, Simon R.,Lindoy, Leonard F.,Plieger, Paul G.,Schroeder, Martin,Tasker, Peter A.
, p. 6090 - 6107 (2008/02/13)
Amide-functionalised salen ligands capable of extracting metal salts have been synthesised and characterised. Single-crystal X-ray structure determinations of complexes of NiSO4, [Ni(L)(SO4)], confirm that the ionophores are in a zwi
Competitive amide hydrolysis in mono- and diformylated ethylenediamines
Petride, Horia,Costan, Oana,Florea, Cristina,Udrea, Silvia
, p. 245 - 253 (2007/10/03)
Alkaline hydrolysis of formylated ethylenediamines of the general structure R1-N(X)-CH2CH2-N(CHO)-R2 (R 1, R2 = H, benzyl, benzoyl; X = H, CHO) was studied in mild conditions. Breaking of the N-C amide bonds took place easily for HN-CHO or (benzoyl)N-CHO, hardly for (benzyl)N-CHO, and did not occur at all for N-COPh. Generally speaking, the various amide bonds underwent hydrolysis according to the following qualitative order of increasing reactivity: PhCO-N(H or alkyl)(alkyl or CHO) ?HCO-N(alkyl)2 1H- and 13C-NMR features of all compounds of interest are presented and discussed. Hindered rotation about the C-N amide bond(s) caused E/Z isomerism in mono- and diformylated derivatives.
Studies on development of sufficiently chemoselective N-acylation reagents: N-Acyl-N-(2,3,4,5,6-pentafluorophenyl)methanesulfonamides
Kondo, Kazuhiro,Sekimoto, Erika,Nakao, Junko,Murakami, Yasuoki
, p. 5843 - 5856 (2007/10/03)
A variety of storable N-acyl-N-(2,3,4,5,6-pentafluorophenyl)methanesulfonamides (4a-e) prepared from N-2,3,4,5,6-pentafluorophenylmethanesulfonamide (3), have been developed after systematic research on the structure-reactivity relationship and were found to serve as N-acylation reagents exhibiting sufficiently good chemoselectivity. (C) 2000 Elsevier Science Ltd.
