676543-67-2Relevant articles and documents
2-Aryl and 2-Heteroaryl Pyrrolo[2,3-b]quinoxalines via Copper-Catalyzed Reaction of 1-Alkynes with 2-Bromo-3-trifluoroacetamidoquinoxaline
Cacchi, Sandro,Fabrizi, Giancarlo,Parisi, Luca M.,Bernini, Roberta
, p. 287 - 290 (2007/10/03)
2-Aryl and 2-heteroaryl pyrrolo[2,3-b]quinoxalines have been prepared in good to high yield through the reaction of 1-alkynes with 2-bromo-3- trifluoroacetamidoquinoxaline in the presence of catalytic amounts of CuI, PPh3, and K2CO3 in dioxane at 110°C. The reaction appears to tolerate a wide range of functionalized 1-alkynes, including those containing ether, alcohol, amide, aldehyde, ketone, ester, and nitro groups.
2,3-Disubstituted pyrrolo[2,3-b]quinoxalines via aminopalladation- reductive elimination
Arcadi, Antonio,Cacchi, Sandro,Fabrizi, Giancarlo,Parisi, Luca M.
, p. 2431 - 2434 (2007/10/03)
2,3-Disubstituted pyrrolo[2,3-b]quinoxalines have been prepared in good to high yield through the reaction of 2-alkynyl-3-trifluoroacetamidoquinoxalines with aryl and vinyl halides or triflates in the presence of Pd(PPh 3)4 and K2CO3 in MeCN at 100°C.