676593-28-5

Upstream product

• 22526-24-5 1-(2-methoxyphenyl)-2,2-dimethyl-1-propanone 
• 676593-24-1 2-isopropenyl-5,5-dimethyl-[1,3,2]dioxaborinane 
• 39615-37-7 2,2-dimethyl-2-[2-(1-methylethenyl)phenyl]propan-1-ol 
• 938-16-9 2,2-dimethylpropiophenone 
• 941320-76-9 1-[2-(dimethylamino)phenyl]-2,2-dimethyl-1-propaone 
• 630-19-3 pivalaldehyde 
• 2142-69-0 2-bromophenyl methyl ketone 
• 7073-70-3 1-bromo-2-isopropenylbenzene 
• 3282-30-2 pivaloyl chloride 
• 698-00-0 2-bromo-N,N-dimethylaniline 

Downstream Products

• 892121-21-0 1-tert-butyl-4-(4-tert-butyl-phenylsulfanylmethyl)-1-methoxy-4-methyl-1,4-dihydro-benzo[d][1,2]dioxine 
• 892121-23-2 1-tert-butyl-4-(4-tert-butyl-phenylsulfanylmethyl)-4-methyl-1,4-dihydro-benzo[d][1,2]dioxin-1-ol 

Relevant academic research and scientific papers

Ruthenium-catalyzed carbon-carbon bond formation via the cleavage of an unreactive aryl carbon-nitrogen bond in aniline derivatives with organoboronates

The RuH2(CO)(PPh3)3-catalyzed reaction of 2-amino-6-methylacetophenone with phenylboronic acid 2,2-dimethyl-1,3-propanediol ester in refluxing toluene gave the corresponding phenylation product in 83% yield via aryl carbon

Regioselective alkenylation of aromatic ketones with alkenylboronates using a RuH2(CO)(PPh3)3 catalyst via carbon - Hydrogen bond cleavage

(Chemical Equation Presented) The ruthenium-catalyzed alkenylation of C-H bonds with alkenylboronates has been explored for a series of aromatic ketones. The coupling reaction of pivalophenone (1) with 2-isopropenyl-5,5-dimethyl[1,3, 2]dioxaborinane (2) g

Ground state oxygen in synthesis of cyclic peroxides. Part 1: Benzo fused ketals

A thiol-olefin-cooxygenation (TOCO) radical chain reaction involving ground state molecular oxygen converts 2′-isopropenyl acetophenones directly into cyclic peroxy hemiketal products with three new bonds. Starting with 4-t-butylbenzenethiol, this TOCO pr

Ruthenium-Catalyzed Functionalization of Aryl Carbon-Oxygen Bonds in Aromatic Ethers with Organoboron Compounds

The ruthenium-catalyzed reaction of aryl ethers having a carbonyl group at the ortho position to the ether group with organoboronates (R?B(OCH2CMe2CH2O), R = aryl, alkenyl, and alkyl) resulted in site-selective C?C bond formation. Among the transition metal complexes screened, the RuH2(CO)(PPh3)3 complex showed the highest activity. Several aromatic ketones having methoxy or phenoxy groups at the ortho position can also be used in this coupling reaction. A variety of arylboronates containing electron-donating (NMe2, OMe, methyl, and vinyl) and -withdrawing (F and CF3) groups reacted with methoxy ketones to give the corresponding coupling products in high yields. Copyright