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2,3,4,6-tetra-O-acetyl-1-S-benzoyl-1-thiohexopyranose is a complex organic compound with the molecular formula C21H23O8S. It is a derivative of hexopyranose, a type of sugar molecule, where four hydroxyl groups are acetylated (replaced by acetyl groups) at the 2, 3, 4, and 6 positions, and a benzoyl group is attached to the sulfur atom at the 1 position. 2,3,4,6-tetra-O-acetyl-1-S-benzoyl-1-thiohexopyranose is often used in organic synthesis and carbohydrate chemistry, particularly in the preparation of various glycosides and other complex carbohydrate structures. Its unique structure allows for the study of sugar derivatives and their interactions in biological systems, making it a valuable tool in the field of biochemistry and pharmaceutical research.

6767-60-8

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6767-60-8 Usage

Type

Synthetic chemical compound.

Field of use

Carbohydrate chemistry.

Structure

A derivative of hexopyranose, a six-membered ring sugar molecule.

Characteristic groups

Four acetyl groups and one benzoyl thioether group attached to the hexopyranose ring.

Common use

Reagent in the synthesis and modification of carbohydrates.

Specific applications

Preparation of glycosides and glycosylamines.

Research relevance

Study of carbohydrate-protein interactions and development of new drugs and therapeutics.

Potential applications

Pharmaceuticals, materials science, and biochemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 6767-60-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,7,6 and 7 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 6767-60:
(6*6)+(5*7)+(4*6)+(3*7)+(2*6)+(1*0)=128
128 % 10 = 8
So 6767-60-8 is a valid CAS Registry Number.

6767-60-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name (3,4,5-triacetyloxy-6-benzoylsulfanyloxan-2-yl)methyl acetate

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6767-60-8 SDS

6767-60-8Downstream Products

6767-60-8Relevant academic research and scientific papers

Modular Synthesis of Aryl Thio/Selenoglycosides via the Catellani Strategy

Ding, Ya-Nan,Huang, Yan-Chong,Shi, Wei-Yu,Zheng, Nian,Wang, Cui-Tian,Chen, Xi,An, Yang,Zhang, Zhe,Liang, Yong-Min

supporting information, p. 5641 - 5646 (2021/08/01)

We described a novel palladium-catalyzed domino procedure for the preparation of (hetero)aryl thio/selenoglycosides. Readily available (hetero)aryl iodides and easily accessible 1-thiosugars/1-selenosugars are utilized as the substrates. Meanwhile, 10 types of sugars are quite compatible with this reaction with good regio- and stereoselectivity, high efficiency, and broad applicability (up to 89%, 53 examples). This method enables the straightforward formation of the C(sp2)-S/Se bond of (hetero)aryl thio/selenoglycosides.

Tri-isopropylsilyl thioglycosides as masked glycosyl thiol nucleophiles for the synthesis of S-linked glycosides and glyco-conjugates

Mandal,Nilsson

supporting information, p. 4816 - 4819 (2014/07/07)

Tri-isopropylsilyl thio-glycosides (TIPS S-glycosides) were synthesized through base promoted SN2 substitution of glycosyl halides with TIPS-SH or by Lewis acid promoted glycosylation of TIPS-SH with glycosyl acetates or p-methoxyphenyl glycosi

Synthesis of thioesters from carboxylic acids via acyloxyphosphonium intermediates with benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent

Gopinath, Purushothaman,Vidyarini, Ravindran Sasitha,Chandrasekaran, Srinivasan

supporting information; experimental part, p. 6291 - 6294 (2009/12/08)

(Chemical Equation Presented) An efficient protocol is reported for the synthesis of thioesters from carboxylic acids with use of acyloxy phosphonium salts as intermediates and benzyltriethyl-ammonium tetrathiomolybdate as the sulfur transfer reagent.

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