67741-16-6

Upstream product

• 14191-95-8 4-cyanomethylphenol 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 
• 79145-99-6 3-(4-hydroxy-phenyl)-2-thioxo-propionic acid 

Downstream Products

• 1376758-56-3 (Z)-3-(4-(dimethylamino)phenyl)-2-(4-hydroxyphenyl)acrylonitrile 
• 1376758-54-1 4-((Z)-1-cyano-2-(4-(dimethylamino)phenyl)vinyl)phenyl methacrylate 
• 66581-99-5 2-hydroxy-5-cyanomethylphenylethan-2-one 
• 156-38-7 4-hydroxyphenylacetate 
• 859800-41-2 3,3-diethoxy-2-[2-(4-hydroxy-phenyl)-acetylamino]-propionic acid 
• 38177-33-2 (4-acetoxyphenyl)acetic acid 
• 65448-20-6 4-acetoxyphenylacetyl chloride 

Relevant academic research and scientific papers

Selective Dual-Channel Imaging on Cyanostyryl-Modified Azulene Systems with Unimolecularly Tunable Visible–Near Infrared Luminescence

Although organic light-emitting molecules have received a growing attention and applicability in modern bioimaging science, the design and control of complex photoluminescent properties in unimolecularly selective imaging remains a challenging topic. Cons

A sensitive AIEE probe for amphiphilic compounds

α-Cyanostilbene substituted with dimethylaniline and hydroxyl groups exhibits profound intensity enhanced bathochromic shifts in an aqueous medium as compared to organic solvents. These conspicuous emission changes are attributed to aggregation as a conse

Nitrile-group-containing azulene-styrene derivatives adopted as near infrared fluorescence probe as well as preparation method and application of nitrile-group-containing azulene-styrene derivative

The invention belongs to the technical field of fluorochrome and particularly relates to nitrile-group-containing azulene-styrene derivatives as well as a preparation method and an application of the nitrile-group-containing azulene-styrene derivatives. T

Ruthenium-Catalyzed Selective Hydroboration of Nitriles and Imines

Ruthenium-catalyzed hydroboration of nitriles and imines is attained using pinacolborane with unprecedented catalytic efficiency. Chemoselective hydroboration of nitriles over esters is also demonstrated. A simple [Ru(p-cymene)Cl2]2 complex (1) is used as a catalyst precursor, which upon reaction with pinacolborane in situ generates the monohydrido-bridged complex [{(η6-p-cymene)RuCl}2(μ-H-μ-Cl)] 2. Further oxidative addition of pinacolborane to intermediate 2 leading to the formation of mononuclear ruthenium hydride species is suggested. Mass spectral analysis of the reaction mixture and independent experiments with phosphine-ligated ruthenium complexes indicated the involvement of mononuclear ruthenium intermediates in the catalytic cycle. Consecutive intramolecular 1,3-hydride transfers from the ruthenium center to coordinated nitrile and boronate imine ligands, leading to the reduction and resulting in the formation of diboronate amines, are proposed as a plausible reaction mechanism.

Cholesterol-tethered AIEE fluorogens: Formation of self-assembled nanostructures

Design and synthesis of cholesterol conjugated chromophores exhibiting intramolecular charge transfer (ICT) and Aggregation Induced Enhanced Emission (AIEE) is described. Cholesterol conjugated α-cyanostilbene exhibits weak emission in organic solvents bu

α-Cyanostilbene based fluorophores: Aggregation-induced enhanced emission, solvatochromism and the pH effect

A series of α-cyanostilbenes substituted with dimethylaniline, diphenylaniline and carbazole was synthesized and their optical spectroscopic properties in homogeneous solvents, the dioxane-water binary mixture and the solid state were investigated. Stilbe

Polymeric temperature and pH fluorescent sensor synthesized by reversible addition-fragmentation chain transfer polymerization

Simple-structured copolymer, poly(NIPMAM-co-CPMA), consisting of N-isopropylmethacrylamide (NIPMAM) and (Z)-4-(1-cyano-2-(4-(dimethylamino) phenyl)vinyl)phenylmethylacrylate (CPMA) units as thermo- and pH-responsive fluorescent signaling parts, respective

PROCESS FOR PREPARATION OF 0-DESMETHYLVENLAFAXINE AND ITS ANALOGUES

The present invention belongs to the field of organic chemistry and refers to a process for the preparation of O-desmethylvenlafaxine (l-[2-Dimethylamino)-l-(4-hydroxyphenyl)ethyl]cyclo- hexanol), its analogues and pharmaceutical acceptable salts thereof. The invention also relates to a catalytic hydrogenation of cyano-group of the substituted acetonitrile.