6780-37-6Relevant academic research and scientific papers
Reactions of N-Acyl-N-(2,2,2-trichloroethylidene)amines with Enamines
Miltz, Wolfgang,Steglich, Wolfgang
, p. 750 - 751 (2007/10/02)
The reaction of N-acyl-N-(2,2,2-trichloroethylidene)amines with cyclic enamines affords chiral 2,2,2-trichloroethyl amine derivatives with high diastereo- and enantioselectivity.
N,N'-DIACYLSELENIUM AND N,N'-DIACYLSULFUR DIIMIDES
Derkach, N. Ya.,Barashenkov, G. G.,Slyusarenko, E. I.
, p. 60 - 66 (2007/10/02)
In the reaction of N,N'-diphenylsulfonylselenium diimide (C6H5SO2N=)2Se with aldehydes, dimethyl sulfoxide, diphenyl selenone, diphenyl selenoxide, triphenylphosphine oxide, etc. the oxygen atom in the E=O group is substituted by a phenylsulfonylimino group.In the reaction of triphenylphosphine with N,N'-diphenylsulfonylselenium diimide N,N'-diphenylsulfonyl-N-triphenylphosphoniohydrazinate is formed.In the reaction of triphenylphosphine with N,N-diacylselenium or N,N'-diacylsulfur sulfimides (CH3CON=)2Se, (C6H5CON=)2Se or (C6H5CON=)2S triphenylphosphine oxide, the corresponding nitrile, and selenium or sulfur are obtained.
