68039-43-0

Basic information

• Product Name: 1-Methoxy-3,5-di-tert-butylbenzene
• Synonyms: 1,3-Bis(1,1-dimethylethyl)-5-methoxybenzene;1,3-Bis(tert-butyl)-5-methoxybenzene;1-Methoxy-3,5-di-tert-butylbenzene
• CAS NO: 68039-43-0
• Molecular Formula: C₁₅H₂₄O
• Molecular Weight: 220.35
• Mol File: 68039-43-0.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 263.4°C at 760 mmHg
• Flash Point: 84.1°C
• Appearance: /
• Density: 0.892g/cm³
• Vapor Pressure: 0.0168mmHg at 25°C
• Refractive Index: 1.476
• CAS DataBase Reference: 1-Methoxy-3,5-di-tert-butylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Methoxy-3,5-di-tert-butylbenzene(68039-43-0)
• EPA Substance Registry System: 1-Methoxy-3,5-di-tert-butylbenzene(68039-43-0)

Safety Data

• Hazardous Substances Data: 68039-43-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H24O/c1-14(2,3)11-8-12(15(4,5)6)10-13(9-11)16-7/h8-10H,1-7H3

Upstream product

• 67-56-1 methanol 
• 22385-77-9 1-bromo-3,5-di-tert-butylbenzene 
• 558-17-8 tert-Butyl iodide 
• 175602-46-7 2,4-di-tert-butyl-6-methoxyphenylboronic acid 
• 3430-17-9 2-bromo-3-picoline 

Downstream Products

• 129633-48-3 trans-2,6-bis(tert-butyl)-4-methoxyphenyl 2-methyl-1,2-dihydro-1-naphthalenecarboxylate 
• 129633-48-3 cis-2,6-bis(tert-butyl)-4-methoxyphenyl 2-methyl-1,2-dihydro-1-naphthalenecarboxylate 
• 129633-53-0 2,6-bis(tert-butyl)-4-methoxyphenyl 1-butyl-1,4-dihydro-2-naphthalenecarboxylate 
• 129633-56-3 2,6-bis(tert-butyl)-4-methoxyphenyl 1-butyl-1,2-dihydro-2-naphthalenecarboxylate 
• 129633-55-2 2,6-bis(tert-butyl)-4-methoxyphenyl 1-phenyl-1,2-dihydro-2-naphthalenecarboxylate 
• 129633-54-1 2,6-bis(tert-butyl)-4-methoxyphenyl 1-methyl-1,4-dihydro-2-naphthalenecarboxylate 
• 129633-57-4 2,6-bis(tert-butyl)-4-methoxyphenyl 1-methyl-1,2-dihydro-2-naphthalenecarboxylate 
• 125973-35-5 naphthalene-2-carboxylic acid 2,6-di-t-butyl-4-methoxyphenyl ester 
• 125973-34-4 2,6-di-tert-butyl-4-(methoxyphenyl)-1-naphthalenecarboxylate 
• 87012-32-6 1,3-di-tert-butyl-5-methoxy-1,4-cyclohexadiene 

Relevant articles and documents

General Paradigm in Photoredox Nickel-Catalyzed Cross-Coupling Allows for Light-Free Access to Reactivity

Self-sustained NiI/III cycles are established as a potentially general paradigm in photoredox Ni-catalyzed carbon–heteroatom cross-coupling reactions through a strategy that allows us to recapitulate photoredox-like reactivity in the absence of light across a wide range of substrates in the amination, etherification, and esterification of aryl bromides, the latter of which has remained, hitherto, elusive under thermal Ni catalysis. Moreover, the accessibility of esterification in the absence of light is especially notable because previous mechanistic studies on this transformation under photoredox conditions have unanimously invoked energy-transfer-mediated pathways.

Base and cation effects on the suzuki cross-coupling of bulky arylboronic acid with halopyridines: Synthesis of pyridylphenols

Strong base and large size cation have been shown to accelerate the rate and the yield of Suzuki coupling of a sterically bulky boronic acid with halopyridines in DME for the synthesis of pyridylphenols.