681-68-5

Basic information

• Product Name: ALLYL 2,2,3,3-TETRAFLUOROPROPYL ETHER
• Synonyms: ALLYL 2,2,3,3-TETRAFLUOROPROPYL ETHER;2,2,3,3-TETRAFLUORO-4-OXA-6-HEPTENE;Allyl 2,2,3,3-tetrafluoropropyl ether 97%;Allyl2,2,3,3-tetrafluoropropylether97%
• CAS NO: 681-68-5
• Molecular Formula: C₆H₈F₄O
• Molecular Weight: 172.12
• Mol File: 681-68-5.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 110°C 740mm
• Appearance: /
• Density: 1,183 g/cm3
• Refractive Index: 1.3471
• CAS DataBase Reference: ALLYL 2,2,3,3-TETRAFLUOROPROPYL ETHER(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL 2,2,3,3-TETRAFLUOROPROPYL ETHER(681-68-5)
• EPA Substance Registry System: ALLYL 2,2,3,3-TETRAFLUOROPROPYL ETHER(681-68-5)

Safety Data

• Hazard Codes: F,Xi
• Statements: 10
• Safety Statements: 16-23-36
• RIDADR: 3271
• HazardClass: IRRITANT, FLAMMABLE
• Hazardous Substances Data: 681-68-5(Hazardous Substances Data)

Usage

General Description

Allyl 2,2,3,3-Tetrafluoropropyl Ether is a synthetic, reactant chemical compound known for its fluoroether property. It has a formula of C6H7F4O. Due to its reactive propyl ether group, this chemical is often used in various industrial applications as an intermediate for synthesizing other compounds. Its precise uses can vary based on the requirements of the specific chemical reactions it's involved in. Like many industrial chemicals, proper handling and safety precautions are necessary when working with Allyl 2,2,3,3-Tetrafluoropropyl Ether due to its reactive and potentially hazardous nature. Therefore, professionals working with this compound need to stay informed about its properties and potential risks. Detailed information about this chemical can typically be found in its Material Safety Data Sheet.

Upstream product

• 19932-26-4 3-((2',2',3',3'-tetrafluoropropanoxy)methyl)oxirane 
• 1137575-85-9 2[(3,3,2,2-tetrafluoropropoxy)methyl]thiirane 
• 110920-07-5 3-[(chlorosulfinyl)oxy]-1,1,2,2-tetrafluoropropane 
• 107-18-6 allyl alcohol 
• 76-37-9 2,2,3,3-tetrafluoropropanol 
• 107-05-1 3-chloroprop-1-ene 

Relevant articles and documents

Features of the reaction of polyfluoroalkyl chlorolsulfites with allyl alcohol

Unlike the saturated aliphatic and aromatic alcohols, allyl alcohol under the same conditions reacts with polyfluoroalkyl chlorosulfites to form not ethers, but polyfluorinated alcohols. The exception is polyfluoroalkyl chlorosulfites with the chain length of more than five carbon atoms. Allyl ethers of polyfluorinated alcohols of general formula CH2=CHCH 2OCH2(CF2CF2)nH (n = 1-3) were obtained, when the reaction proceeded in the presence of potassium carbonate, owing to its participation in a specific orientation of the reaction centers in the resulting intermediate structure, which is easily transformed into allyl ethers of polyfluorinated alcohols. Pleiades Publishing, Ltd., 2011.

Thermal desulfurization of (Alkoxymethyl)thiiranes

Reaction of (alkoxymethyl)oxiranes with thiourea in methanol has afforded the corresponding thiiranes, and catalyst-free thermal desulfurization of the products has been studied. The major products of desulfurization are alcohols and alkenes, both in the cases of (polyfluoroalkyloxymethyl)thiiranes and their non-fluorinated analogs. Longer alkyl chain in thiiranes favors formation of alcohols over alkenes formation in the course of desulfurization.