Allyl 2,2,3,3-tetrafluoropropyl ether

Base Information

• Chemical Name: Allyl 2,2,3,3-tetrafluoropropyl ether
• CAS No.: 681-68-5
• Molecular Formula: C6H8F4O
• Molecular Weight: 172.123
• Hs Code.: 2909199090
• DSSTox Substance ID: DTXSID60382617
• Wikidata: Q82173975
• Mol file: 681-68-5.mol

Synonyms:Allyl 2,2,3,3-tetrafluoropropyl ether;681-68-5;3-(2,2,3,3-tetrafluoropropoxy)prop-1-ene;1,1,2,2-tetrafluoro-3-prop-2-enoxypropane;MFCD02093319;SCHEMBL5881269;DTXSID60382617;MEIXYCHYADMPTF-UHFFFAOYSA-N;AKOS006230021;3-allyloxy-1,1,2,2-tetrafluoro-propane;FT-0676778;A836039

Chemical Property of Allyl 2,2,3,3-tetrafluoropropyl ether

Chemical Property:

• Refractive Index: 1.3471
• Boiling Point: 110°C 740mm
• PSA: 9.23000
• Density: 1,183 g/cm3
• LogP: 2.08940
• XLogP3: 2.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 5
• Exact Mass: 172.05112752
• Heavy Atom Count: 11
• Complexity: 124

Purity/Quality:

98%Min ^*data from raw suppliers

Allyl2,2,3,3-TetrafluoropropylEther ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 10
• Safety Statements: 16-23-36

MSDS Files:

Useful:

• Canonical SMILES: C=CCOCC(C(F)F)(F)F

Technology Process of Allyl 2,2,3,3-tetrafluoropropyl ether

There total 4 articles about Allyl 2,2,3,3-tetrafluoropropyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2,2,3,3-tetrafluoropropanol (76-37-9) + 3-chloroprop-1-ene (107-05-1) → 3-(2,2,3,3-tetrafluoropropoxy)-1-propene (681-68-5)

Guidance literature:

With 50percent iger natronlauge; tetrabutyl-ammonium chloride; at 40 ℃; for 10h; Product distribution; other α,α',ω-trihydroperfluoroalcoholes, other reagents; var. solvents; var. times and temp.;

DOI:10.1016/0022-328X(91)86270-Z

Reference yield: 66.2%

3-[(chlorosulfinyl)oxy]-1,1,2,2-tetrafluoropropane (110920-07-5) + allyl alcohol (107-18-6) → 3-(2,2,3,3-tetrafluoropropoxy)-1-propene (681-68-5)

Guidance literature:

With potassium carbonate; In chloroform; at -15 - 30 ℃;

DOI:10.1134/S107036321108010X

Reference yield: 51.0%

2[(3,3,2,2-tetrafluoropropoxy)methyl]thiirane (1137575-85-9) → 2,2,3,3-tetrafluoropropanol (76-37-9) + 3-(2,2,3,3-tetrafluoropropoxy)-1-propene (681-68-5) + C6H8F4O

Guidance literature:

at 210 - 215 ℃;

DOI:10.1134/S1070363214110139

upstream raw materials:

2,2,3,3-tetrafluoropropanol

3-chloroprop-1-ene

3-[(chlorosulfinyl)oxy]-1,1,2,2-tetrafluoropropane

allyl alcohol