6833-18-7

Basic information

• Product Name: 4-METHYLBENZANILIDE
• Synonyms: P-TOLUANILIDE;P-METHYL BENZANILIDE;AKOS 244-40;4-TOLUANILIDE;4-METHYLBENZANILIDE;N-Phenyl-4-methylbenzamide;N-Phenyl-p-toluamide;BenzaMide, 4-Methyl-N-phenyl-
• CAS NO: 6833-18-7
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.26
• Product Categories: Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
• Mol File: 6833-18-7.mol
• Article Data: 189

Chemical Properties

• Melting Point: 183 °C
• Boiling Point: 277.716°C at 760 mmHg
• Flash Point: 163.142°C
• Appearance: /
• Density: 1.145g/cm³
• Vapor Pressure: 0.004mmHg at 25°C
• Refractive Index: 1.63
• PKA: 13.76±0.70(Predicted)
• CAS DataBase Reference: 4-METHYLBENZANILIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-METHYLBENZANILIDE(6833-18-7)
• EPA Substance Registry System: 4-METHYLBENZANILIDE(6833-18-7)

Safety Data

• Hazardous Substances Data: 6833-18-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H13NO/c1-11-7-9-12(10-8-11)14(16)15-13-5-3-2-4-6-13/h2-10H,1H3,(H,15,16)

Upstream product

• 79-37-8 oxalyl dichloride 
• 60-29-7 diethyl ether 
• 2998-92-7 (Z)-phenyl(p-tolyl)methanone oxime 
• 14338-21-7 tri-(4-methylphenyl)aluminum 
• 103-71-9 phenyl isocyanate 
• 874-60-2 4-methyl-benzoyl chloride 
• 62-53-3 aniline 
• 1900-85-2 phenyl p-methylbenzoate 
• 142-04-1 aniline hydrochloride 
• 38032-15-4 (4-methylphenyl)phenylmethanone oxime 
• 7446-70-0 aluminium trichloride 
• 108-88-3 toluene 
• 10026-13-8 phosphorus pentachloride 
• 2998-91-6 p-tolyl phenyl ketoxime 

Downstream Products

• 68587-15-5 (4-(dimethylamino)phenyl)(p-tolyl)methanone 
• 25110-49-0 4-methyl-N,N'-diphenyl-benzamidine 
• 40686-26-8 4-Methyl-N,N-diphenylbenzamide 
• 1027895-70-0 2-[Hydroxy-(3-methoxy-phenyl)-methyl]-4-methyl-N-phenyl-benzamide 
• 329969-90-6 [1-Benzotriazol-1-yl-1-p-tolyl-meth-(E)-ylidene]-phenyl-amine 
• 100-21-0 terephthalic acid 
• 34916-13-7 N-Phenyl-p-toluol-carboximidsaeure-chlorid 
• 161768-67-8 N-[(Z)-1H-1,2,3-benzotriazol-1-yl(4-methylphenyl)methylidene]aniline 
• 93-98-1 N-phenyl benzoyl amide 
• 5436-83-9 N-benzyl-4-methylbenzamide 
• 1069123-79-0 2-p-tolyl-1H-indole-3-carboxylic acid ethyl ester 
• 15818-64-1 N-(4-methylbenzyl)aniline 
• 106-42-3 para-xylene 
• 2362-77-8 (4-methylbenzylidene)phenylamine 

Relevant articles and documents

Water-Soluble Non-Classical Benzene Mimetics

A new generation of saturated benzene mimetics, 2-oxabicyclo[2.1.1]hexanes, was developed. These compounds were designed as analogues of bicyclo[1.1.1]pentane with an improved water solubility. Crystallographic analysis of 2-oxabicyclo[2.1.1]hexanes revea

Visible-Light Carbon Nitride-Catalyzed Aerobic Cyclization of Thiobenzanilides under Ambient Air Conditions

A metal-free heterogeneous photocatalysis has been developed for the synthesis of benzothiazoles via intramolecular C-H functionalization/C-S bond formation of thiobenzanilides by inexpensive graphitic carbon nitride (g-C3N4) under visible-light irradiation. This reaction provides access to a broad range of 2-substituted benzothiazoles in high yields under an air atmosphere at room temperature without addition of a strong base or organic oxidizing reagents. In addition, the catalyst was found to be stable and reusable after five reaction cycles.

Selective hydrogenation dehalogenation method of ortho-halogenated acylaniline

The invention discloses a selective hydrogenation dehalogenation method of copper-catalyzed ortho-halogenated acylaniline. The method comprises the following steps: by using ortho-halogenated acylaniline as a starting raw material and copper acetylacetonate/vasicine as a catalyst, adding an organic alkali, reacting in an alcoholic solution at 80-100 DEG C for 12 hours, and regioselectively catalytically hydrogenating ortho-bromine and iodine atoms. The preparation method has the characteristics of simplicity and convenience in operation, wide substrate application range, low cost, high regioselectivity and the like, and has practicability.