68330-44-9

Basic information

• Product Name: (1S)-EXO-1,2,7,7-TETRAMETHYLBICYCLO[2.2.1]HEPTAN-2-OL
• Synonyms: (1S)-EXO-1,2,7,7-TETRAMETHYLBICYCLO[2.2.1]HEPTAN-2-OL;(S)-(-)-EXO-2-METHYLISOBORNEOL;(S)-(+)-2-METHYL-EXO-ISOBORNEOL
• CAS NO: 68330-44-9
• Molecular Formula: C11H20O
• Molecular Weight: 168.28
• Mol File: 68330-44-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 208.7±8.0 °C(Predicted)
• Appearance: /
• Density: 0.968±0.06 g/cm3(Predicted)
• PKA: 15.43±0.60(Predicted)
• CAS DataBase Reference: (1S)-EXO-1,2,7,7-TETRAMETHYLBICYCLO[2.2.1]HEPTAN-2-OL(CAS DataBase Reference)
• NIST Chemistry Reference: (1S)-EXO-1,2,7,7-TETRAMETHYLBICYCLO[2.2.1]HEPTAN-2-OL(68330-44-9)
• EPA Substance Registry System: (1S)-EXO-1,2,7,7-TETRAMETHYLBICYCLO[2.2.1]HEPTAN-2-OL(68330-44-9)

Safety Data

• Hazardous Substances Data: 68330-44-9(Hazardous Substances Data)

Usage

General Description

(1S)-EXO-1,2,7,7-tetramethylbicyclo[2.2.1]heptan-2-ol is a bicyclic terpene alcohol with the molecular formula C10H20O. It is a colorless liquid with a characteristic odor and is commonly found in the fragrance and flavor industries. It is naturally found in a variety of plants and is used as a key ingredient in the production of perfumes, cosmetics, and flavorings. It has been reported to exhibit various biological activities, including antimicrobial, anti-inflammatory, and antioxidant properties. Additionally, it has been used in traditional medicine for its potential therapeutic benefits. Overall, (1S)-EXO-1,2,7,7-tetramethylbicyclo[2.2.1]heptan-2-ol is a versatile chemical compound with a wide range of applications and potential health benefits.

Upstream product

• 464-48-2 (1S)-camphor 
• 676-58-4 methylmagnesium chloride 
• 83997-36-8 (1S,2S,4S)-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,2'-oxirane] 
• 75-16-1 methylmagnesium bromide 

Relevant articles and documents

Regiodivergent Hydroborative Ring Opening of Epoxides via Selective C-O Bond Activation

A magnesium-catalyzed regiodivergent C-O bond cleavage protocol is presented. Readily available magnesium catalysts achieve the selective hydroboration of a wide range of epoxides and oxetanes yielding secondary and tertiary alcohols in excellent yields and regioselectivities. Experimental mechanistic investigations and DFT calculations provide insight into the unexpected regiodivergence and explain the different mechanisms of the C-O bond activation and product formation.

Synthesis of 2,2,-Disubstituted Oxetanes from Ketones with S-Methyl-S-(sodiomethyl)-N-(4-tolylsulfonyl)sulfoximine

A covenient and facile one-step synthesis of 2,2-disubstituted oxetanes from ketones utilizing S-methyl-S-(sodiomethyl)-N-(4-tolylsulfonyl)sulfoxymine in dimethyl sulfoxide is presented.The stereochemistry and chemical reactivity of some 2,2-disubstituted