68342-69-8Relevant academic research and scientific papers
Direct synthesis of oxazolines from olefins and amides using t-BuOI
Minakata, Satoshi,Morino, Yoshinobu,Ide, Toshihiro,Oderaotoshi, Yoji,Komatsu, Mitsuo
, p. 3279 - 3281 (2008/02/13)
A new and simple method for the synthesis of oxazolines from readily accessible olefins and amides using tert-butyl hypoiodite is described; aromatic/aliphatic olefins and amides can be used in the reaction to give a variety of oxazolines. The Royal Socie
Intermediate Substitution in the Formation of a Benzylic Anion by an Aromatic Radical Anion as Observed with 1-Benzoyl-2-phenylaziridine
Stamm, Helmut,Falkenstein, Reinhart
, p. 2227 - 2230 (2007/10/02)
The reaction of the title compound 1 with anthracene hydride AH(-) or anthracenide A(-*) leads to the formation of the benzylic anion 9 by fragmentation of the first generated substitution intermediate 7 or 8.In the reactions with AH(-) the carbanion 9 is completely trapped by protonation with dihydroanthracene AH2 yielding the reduction product 3 (N-benzoyl-phenethylamine).In reactions with A(-*) as well as with naphthalenide N(-*) the carbanion 9 either abstracts a proton from the solvent THF (yielding 3) or adds to the benzoyl group of unreacted 1 which finally results in β-benzamido-α-phenylpropiophenone (6).
