687-64-9

Basic information

• Product Name: methyl lysinate
• Synonyms: methyl lysinate;(2S)-2,6-Diaminohexanoic acid methyl ester;L-Lysine methyl;Lysine methyl;Einecs 211-697-8;methyl L-lysinate;L-Lysine methylester, [3H]-
• CAS NO: 687-64-9
• Molecular Formula: C₇H₁₆N₂O₂
• Molecular Weight: 160.21414
• EINECS: 211-697-8
• Mol File: 687-64-9.mol
• Article Data: 18

Chemical Properties

• Appearance: /
• CAS DataBase Reference: methyl lysinate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl lysinate(687-64-9)
• EPA Substance Registry System: methyl lysinate(687-64-9)

Safety Data

• Hazardous Substances Data: 687-64-9(Hazardous Substances Data)

Usage

Definition

ChEBI: The L-lysyl ester formed by conjugating L-lysine with methanol.

InChI:InChI=1/C7H16N2O2/c1-11-7(10)6(9)4-2-3-5-8/h6H,2-5,8-9H2,1H3

Upstream product

• 67-56-1 methanol 
• 56-87-1 L-lysine 
• 4117-33-3 L-Lysine ethyl ester 
• 657-27-2 L-Lysine hydrochloride 
• 923-27-3 D-lysine 
• 13515-95-2 lysine methyl ester dihydrochloride 
• 77-76-9 2,2-dimethoxy-propane 
• 2483-48-9 (+)-(S)-N₂,N₆-bis[(1,1-dimethylethoxy)carbonyl]-lysine methyl ester 
• 3017-32-1 (S)-methyl 2-amino-6-(tert-butoxycarbonylamino)hexanoate 
• 172846-56-9 methyl N²-(((9H-fluoren-9-yl)methoxy)carbonyl)-N⁶-(tert-butoxycarbonyl)-L-lysinate 
• 71989-26-9 Fmoc-Lys(tert-butoxycarbonyl) 
• 70-54-2 2,6-diaminocaproic acid 
• 617-68-5 Lysin-dihydrochlorid 
• 55757-60-3 N-α-(tert-butoxycarbonyl)-L-lysine methyl ester 

Downstream Products

• 1478-74-6 N,N'-di(trifluoroacetyl)-L-lysine methyl ester 
• 17045-07-7 (S)-2,6-bis-(2,4-dinitro-anilino)-hexanol 
• 4383-81-7 D-Lysin-hydroxamsaeure 
• 145401-88-3 N^α,N^ε-bis<(R)-α-methylbenzylcarbamoyl>-DL-lysine methyl ester 
• 103954-34-3 (2S,1'R)-N⁶-<1-(Ethoxycarbonyl)ethyl>lysin-methylester 
• 103954-34-3 (2R,1'R)-N⁶-<1-(Ethoxycarbonyl)ethyl>lysin-methylester 
• 103954-36-5 (2S,1'S)-N⁶-<1-(Ethoxycarbonyl)ethyl>lysin-methylester 
• 35677-83-9 methyl (S)-pipecolinate 
• 2483-48-9 (+)-(S)-N₂,N₆-bis[(1,1-dimethylethoxy)carbonyl]-lysine methyl ester 
• 21653-99-6 L-lysine 
• 521334-60-1 (S)-6-Amino-2-{6-[3-(2-phenylethynyl-cyclohex-1-enylethynyl)-phenyl]-hexanoylamino}-hexanoic acid 
• 651778-37-9 (S)-2,6-Bis-(2,6-bis-benzoylamino-hexanoylamino)-hexanoic acid methyl ester 
• 651778-33-5 2,6-bis-(2,6-bis-benzoylamino-hexanoylamino)-hexanoic acid methyl ester 
• 335265-92-4 4,14-dibenzyl-2,5,13,16-tetraoxo-3,6,12,15,21-pentaazabicyclo[15,3,1]heneicosa-1⁽²¹⁾,17⁽¹⁸⁾,19-triene-11-carboxylic acid methyl ester 

Relevant articles and documents

Synthesis of peptide dendrimers with polyhedral oligomeric silsesquioxane cores via click chemistry

Inorganic polyhedral oligomeric silsesquioxane (POSS) was used as the core for the synthesis of poly(l-lysine) peptide dendrimer via copper-catalyzed azide-alkyne click chemistry. The inorganic/organic composite dendrimer was characterized by MS, 1/

Preparation method of amino-acid ester

The invention relates to a preparation method of amino-acid ester, and belongs to the field of synthesis of organic compounds. The preparation method of the amino-acid ester comprises the following steps: taking sulfur trioxide as a catalyst and a water-binding agent, catalyzing amino acid and alcohol to react so as to prepare sulfate of the amino-acid ester, then concentrating a reaction system to remove a reaction solvent and then adding water for dissolving, and neutralizing ammonia water to prepare the amino-acid ester. According to the technical scheme, the provided preparation method ofthe amino-acid ester has the advantages of mild reaction process, high yield, good purity, simplicity in operation and low cost. Concentrated condensate water of central mother liquor of the preparation method of the amino-acid ester can be directly subjected to biochemical treatment, solid by-products are high-purity ammonium sulfate, and can serve as chemical fertilizers, a reaction process is green and pollution-free, and thus, environmental protection is facilitated.

Metalloporphyrin dimers bridged by a peptoid helix: Host-guest interaction and chiral recognition

Co-facial porphyrins have been designed to construct porphyrin tweezers with versatile molecular recognition capabilities. In this study, we synthesized metalloporphyrin-peptoid conjugates (MPPCs) displaying two metalloporphyrins on a peptoid scaffold with either achiral unfolded (1) or helical (2 and 3) secondary structures. Host-guest complexation of MPPCs was realized with various guests of different lengths and basicities, and the extent of complexation was measured by UV-vis and circular dichroism (CD) spectroscopic titration. Intermolecular and intramolecular chirality induction were observed on achiral and chiral peptoid backbones, respectively. Spectroscopic data indicated that a broad scope of achiral guests can be recognized by chiral 2; in particular, longer and more flexible guests were seen to bind more tightly on 2. In addition, chiral 2 provided a distinct CD couplet with DL-, D-, or L-Lys-OMe, which was a result of the diastereomeric host-guest complex formation. Our results indicated that MPPCs can recognize, contrast, and analyze various achiral, chiral, or racemic molecules. Based on co-facial metalloporphyrins present on peptoid scaffolds, we developed a novel class of porphyrin tweezers, which can be further utilized in asymmetric catalysis, molecular sensing, and drug delivery.