6873-86-5

Upstream product

• 67-64-1 acetone 
• 188447-91-8 (S)-p-toluenesulfinimide 
• 672-78-6 (-)-(S)-methyl toluene-p-sulphinate 
• 75-31-0 isopropylamine 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 1858-86-2 Ethyl p-toluenesulfinate 

Downstream Products

• 116560-16-8 [Isopropyl-(toluene-4-sulfinyl)-amino]-acetic acid tert-butyl ester 
• 1059194-07-8 C₂₂H₂₇BNOPS 
• 27094-01-5 N-isopropyl-N-diphenylphosphinyl-p-toluolsulfinamid 
• 111289-39-5 [Isopropyl-((S)-toluene-4-sulfinyl)-amino]-acetic acid tert-butyl ester 
• 105-36-2 ethyl bromoacetate 
• 145835-13-8 ethyl 2-(p-tolylsulfinyl)acetate 
• 672-78-6 methyl p-toluene sulfinate 
• 116560-15-7 4-Methyl-benzenesulfinic acid isopropyl-methyl-amide 
• 21230-07-9 N-isopropyl-p-toluenesulfonamide 
• 36160-75-5 C₁₃H₁₉NO₃S 
• 36160-74-4 2-[Isopropyl-(toluene-4-sulfinyl)-amino]-N-propyl-acetamide 

Relevant academic research and scientific papers

N-phosphino-p-tolylsulfinamide ligands: Synthesis, stability, and application to the intermolecular Pauson-Khand reaction

(Chemical Equation Presented) Here we synthesized a family of racemic and optically pure N-phosphino-p-tolylsulfinamide (PNSO) ligands. Their stability and coordination behavior toward dicobalt-alkyne complexes was evaluated. Selectivities of up to 3:1 we

Electrochemical oxidation of N-p-toluenesulfinamides

Matrix presented Contrasting and interesting electrochemical behavior is observed in anodic oxidation of N-substituted p-toluenesulfinamides under controlled current conditions. For sulfinamides derived from secondary alkylamines and primary arylamines, the N-sulfinyl group is removed and the corresponding amines are formed; for sulfinamides derived from primary alkylamines, sulfur oxidation yields the corresponding sulfonamides in good yields.

Syntheses and Reactions of Optically Active Alkyltoluene-p-sulphinamides. Part 2. Substitution at Sulphur with Retention of Configuration

The stereochemistry of the reaction of optically active sulphonamides (1a-c) with different alkylating agents has been examined.The electrophilic attack on sulphoximidate anions occurs only at nitrogen.Prevailing retention of configuration at sulphur (e.e. up to 48percent) is observed in the formation of p-tolylsulphinyl acetates from sulphinamides (1b-c) with α-bromo esters.