95896-89-2

Basic information

• Product Name: Cyclohexene, 3-iodo-
• CAS NO: 95896-89-2
• Molecular Formula: C6H9I
• Molecular Weight: 208.042
• Mol File: 95896-89-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 3-iodo-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 3-iodo-(95896-89-2)
• EPA Substance Registry System: Cyclohexene, 3-iodo-(95896-89-2)

Safety Data

• Hazardous Substances Data: 95896-89-2(Hazardous Substances Data)

Upstream product

• 68735-62-6 cyclohexen-1-en-3-yl diethyl phosphate 
• 113353-45-0 trimethylstannyl cyclohex-2-enylsulfinate 
• 1521-51-3 rac-3-bromocyclohexene 
• 110-83-8 cyclohexene 
• 507-02-8 acetyl iodide 
• 7553-56-2 iodine 
• 822-67-3 Cyclohex-2-enol 

Downstream Products

• 82700-05-8 2-(cyclohex-2-en-1-yl)acetonitrile 
• 1182228-61-0 (-)-(R)-(2-(cyclohex-2-enyl)ethyl)benzene 
• 1182228-47-2 (S)-(+)-(2-(cyclohex-2-en-1-yl)ethyl)benzene 
• 822-67-3 Cyclohex-2-enol 
• 930-68-7 cyclohexenone 

Relevant articles and documents

One-Pot Synthesis of Homoallylic Alcohols via a Facile Conversion of Allylic Alcohols into Allylic Iodides

Allylic alcohols were readily converted into allylic iodides by hydrogen iodide generated in situ from chlorotrimethylsilane/sodium iodide and water, or alcohols, under mild conditions.Displacement of allylic alcahols containing a terminal double bond gave allylic iodides accomponied by allylic rearrangement.This procedure has successfully been extended to a one-pot synthesis of homoallylic alcohols by carrying out successive Barbier type reactions.

Photochemical reaction of acyl iodides with alkenes and thiophene

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The thermal desulfination of allylic sulfonyl halides

Allylic sulfonyl halides can be generated by halogenolysis of the corresponding triorganotin sulfinates. Allylic sulfonyl bromides and iodides undergo a first order, thermal desulfination with allylic rearrangement to yield the corresponding allylic halides. The desulfination of a cyclic allylic sulfonyl bromide is stereospecific, proceeding with γ-syn bromine migration.