68898-62-4Relevant academic research and scientific papers
CURABLE COMPOSITIONS, PRODUCTS AND ARTICLES FORMED THEREFROM, AND METHODS OF FORMING THE SAME
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Paragraph 0020; 0047, (2020/08/22)
A curable composition, a method of making the curable composition, and an article and product produced therefrom are provided. A morpholinedione is contacted with an isocyanate to form a resin composition. The resin composition is reacted with an amine to form the curable composition. Such curable compositions include adhesives, coatings, castings, sealants, elastomers, and foams. After curing, the morpholinedione-derived compositions exhibit improved performance properties such as microhardness, cross-hatch adhesion, and solvent resistance compared to analogous compositions not made with morpholinedione.
Efficient functionalization of oligonucleotides by new achiral nonnucleosidic monomers
Kupryushkin, Maxim S.,Nekrasov, Mikhail D.,Stetsenko, Dmitry A.,Pyshnyi, Dmitrii V.
supporting information, p. 2842 - 2845 (2014/06/23)
A novel synthetic strategy has been designed for preparation of achiral nonnucleosidic phosphoramidite monomers for automated solid-phase oligonucleotide synthesis. It is based on O-DMTr-protected 4-(2-hydroxyethyl)- morpholine-2,3-dione as the key compound and a family of building blocks obtained by its ring-opening by primary aliphatic amines. A series of nonnucleosidic phosphoramidites containing various side-chain functionalities was synthesized, and corresponding oligodeoxyribonucleotides incorporating modified units in single or multiple positions along the chain were prepared.
Oligonucleotide functionalization by a novel alkyne-modified nonnucleosidic reagent obtained by versatile building block chemistry
Kupryushkin, Maxim S.,Konevetz, Dmitrii A.,Vasilyeva, Svetlana V.,Kuznetsova, Anastasia S.,Stetsenko, Dmitry A.,Pyshnyi, Dmitrii V.
, p. 306 - 319 (2013/08/26)
A convenient synthetic strategy has been designed to prepare an alkyne-modified synthon for automated DNA synthesis. It is based on the key O-DMTr-protected 4-(2-hydroxyethyl)morpholin-2,3-dione and building blocks obtained by its functionalization by var
Convenient method for the synthesis of phosphoramidite non-nucleotide inserts for preparation of functionalized oligonucleotides
Kupryushkin,Pyshnyi
, p. 662 - 666 (2013/02/25)
A simple approach to the synthesis of amidophosphite synthons of achiral non-nucleotide inserts using 4-(2-(4,4'-dimethoxytrityloxy)ethyl)morpholine-2,3- dione as a backbone of key precursor was suggested. Non-nucleotide synthons were synthesized using this approach that were suitable for synthesis of acridine-containing oligonucleotide derivatives, as well as oligonucleotides with branched carbohydrate-phosphate backbone. Pleiades Publishing, Ltd., 2012.
Compound containing an oxamic acid group, a process for producing the compound, and a resin composition containing the compound
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, (2008/06/13)
The present invention relates to compounds containing an oxamic acid group, which show high reactivity and have stability for water and are used as paints, adhesives, and plastic materials etc. in the form of a reaction material or a resin. Since into these compounds an oxamic acid group is introduced in a part of the molecule and the oxamic acid group is an ionic functional group, the compounds show superior solubility and dispersing character in water and also, since the oxamic acid group is a group of a disappearing type with heating, the compounds do not remain, after hardening, in the hardened product. Accordingly, the hardened products obtained from these compounds are superior in water-resistant and anticorrosion properties and in durability.
