69112-08-9

Usage

Uses

Used in Chemical Synthesis:
3,3'-dibromo-4,4'-bipyridine is used as an intermediate in the synthesis of antimony and bismuth-bridged bipyridyls. These compounds have potential applications in various fields, including pharmaceuticals, materials science, and catalysis.
Used in Research and Development:
As a research chemical, 3,3'-dibromo-4,4'-bipyridine is employed in the development and testing of new chemical reactions, methodologies, and processes. It serves as a valuable tool for chemists to study the reactivity and properties of bipyridine-based compounds, which can lead to the discovery of new materials and pharmaceuticals.
Used in Pharmaceutical Industry:
3,3'-dibromo-4,4'-bipyridine may be used as a building block or a precursor in the development of new drugs, particularly those targeting various diseases and conditions. Its unique structure and reactivity make it a promising candidate for the design of novel therapeutic agents.
Used in Materials Science:
In the field of materials science, 3,3'-dibromo-4,4'-bipyridine could be utilized in the creation of new materials with specific properties, such as conductivity, magnetism, or optical characteristics. Its incorporation into polymers, coordination complexes, or other molecular structures can lead to the development of advanced materials with potential applications in electronics, sensors, and energy storage.
Overall, 3,3'-dibromo-4,4'-bipyridine is a versatile compound with a wide range of potential applications across various industries, including pharmaceuticals, materials science, and chemical synthesis. Its use as a research chemical further highlights its importance in the development of new technologies and products.

Upstream product

• 626-55-1 3-Bromopyridine 

Downstream Products

• 1333225-60-7 2,7-diazadibenzophosphole oxide 
• 1531588-55-2 1,1-diphenyldipyridinosilole 
• 1531588-56-3 bis(methoxyphenyl)dipyridinosilole 
• 1531588-57-4 1,1-diphenyldipyridinogermole 

Relevant academic research and scientific papers

“Tetramethylsilanoviologen”: Synthesis, characterization, and hydrolysis of a Silolodipyridinium ion

A silicon-bridged viologen has been synthesized by methylation of 4,4′-dipyridinodimethylsilole, and represents a new addition to the growing family of heteroatom bridged viologens. The dicationic species emits at 360?nm and exhibits two chemically reversible one electron reduction waves in acetonitrile at E1/2?(2+/1+)?=??0.829?V and E1/2?(1+/0)?=??1.307?V (versus Fc/Fc+). The UV–Vis spectrum for each of the three charge states is similar to the corresponding unbridged methyl viologen species. The silanoviologen is susceptible to ring-opening hydrolysis.

Narrow-Bandgap Chalcogenoviologens for Electrochromism and Visible-Light-Driven Hydrogen Evolution

A series of electron-accepting chalcogen-bridged viologens with narrow HOMO–LUMO bandgaps and low LUMO levels is reported. The optoelectronic properties of chalcogenoviologens can be readily tuned through heavy atom substitution (S, Se and Te). Herein, in situ electrochemical spectroscopy was performed on the proof-of-concept electrochromic devices (ECD). E-BnV2+ (E=Se, Te; BnV2+=benzyl viologen) was used for the visible-light-driven hydrogen evolution due to the strong visible-light absorption. Remarkably, E-BnV2+ was not only used as a photosensitizer, but also as an electron mediator, providing a new strategy to explore photocatalysts. The higher apparent quantum yield of Se-BnV2+ could be interpreted in terms of different energy levels, faster electron-transfer rates and faster formation of radical species.

Synthesis and properties of thieno[2,3-d:5,4-d']bisthiazoles and their oxidized derivatives: Thionyl chloride as a sulfurative ring-fusing reagent towards thiophene-based ring-fused heteroaromatic compounds

A new route to thiophene-ring-fused compounds with thionyl chloride as a sulfur source was developed. Use of an excess amount thionyl chloride directly gave the corresponding thiophene-ring-fused compound via further reduction of generated thiophene-S-oxide with excess thionyl chloride in some cases. One-pot reduction with tributylphosphine also gave thiophene-ring-fused compounds in good yields, and oxidation with NaClO·5H2O gave S-dioxides. In addition, one of the obtained thiazole-thiophene ring-fused compounds showed some unexpected mechanochromism behavior.

Side-Group-Mediated Mechanical Conductance Switching in Molecular Junctions

A key target in molecular electronics has been molecules having switchable electrical properties. Switching between two electrical states has been demonstrated using such stimuli as light, electrochemical voltage, complexation and mechanical modulation. A

ORGANIC COMPOUND AND ORGANIC OPTOELECTRONIC DEVICE AND DISPLAY DEVICE

The present invention relates to an organic compound represented by chemical formula 1, an organic optoelectronic device including the organic compound, and a display device. In the chemical formula 1, X^1 to X^8, L^1, R^1, and A^1 are as described in the specification. One embodiment of the present invention provides an organic compound capable of implementing a high efficiency and long-lived organic optoelectronic device.COPYRIGHT KIPO 2017

3,7-diazadibenzophosphole oxide: A phosphorus-bridged viologen analogue with significantly lowered reduction threshold

Phosphorus pulls its weight: Installation of a phosphoryl group as central bridge in the 4,4′-bipyridine scaffold introduces improved reduction responses that become even more pronounced in the corresponding phosphoryl-bridged methylviologen (see picture)