692-45-5Relevant articles and documents
PROCESS INCLUDING HYDROGENOLYSIS OF BIOMASS FOLLOWED BY DEHYDROGENATION AND ALDOL CONDENSATION FOR PRODUCING ALKANES
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Page/Page column 34-37, (2011/12/02)
A method comprises providing a bio-based feedstock; contacting the bio-based feedstock with a solvent in a hydrolysis reaction to form an intermediate stream comprising carbohydrates; contacting the intermediate stream with an aqueous phase reforming catalyst to form a plurality of oxygenated intermediates, wherein a first portion of the oxygenated intermediates are recycled to form the solvent; and contacting at least a second portion of the oxygenated intermediates with a condensation catalyst comprising a base functionality to form a fuel blend.
A novel synthesis of vinyl esters from vinylversatate-10
Mondal,Van Der Meer,German,Heikens
, p. 4205 - 4207 (2007/10/05)
Vinylversatate-10 (VV10)1 1 VV 10 Vinyl Monomer, Development Product, Shell Chemical Company has successfully been used to synthesise a large number of lower vinyl esters by transvinylation in presence of mercuric acetate and sulfuric acid. The synthesis of vinylhalo esters proceeds with more difficulty. It has been observed that neither Hg(OAc)2 nor H2SO4 alone is capable of initiating the transvinylation. Furthermore, it has been found that a molar ratio 2:1 of VV10 to carboxylic acid is sufficient to drive the reaction to the right by continuous distillation of the vinyl ester formed, and as a result a high yield of vinyl ester is obtained. A mechanism for this reaction and for the formation of side products has been proposed.